GCMS volatile organic compound results, Mar 8 2002

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Data File C:\HPCHEM\1\DATA\FEB2102\CAL4 0B.D Vial: 2 Acq On 23 Feb 2002 10:28 am Operator : Sample Inst : GC/MS 209 Mise Multiplr: 1.00 MS Integration Params: GOOFY.P Quant Time: Feb 27 14:18 2002 Quant Results File: GCMS0208.RES

Quant Method : C:\HPCHEM\1\METHODS\GCMS0208.M (RTE Integrator) Title : 209 625/TCLP calibration table Last Update : Wed Feb 27 11:30:15 2002 Response via : Initial Calibration DataAcq Meth : GCMS0208

Internal Standards R.T. Qlon Response Cone Units Dev(Min)

1) 1,4-Dichlorobenzene-d4 12.34 152 302758 20.00 ug/1 -0.02 10) Naphthalene-d8 15.98 136 1200876 20.00 ug/1 -0.02 17) Acenaphthene-diO 21.30 164 636333 20.00 ug/1 -0.02 29) Phenanthrene-diO 25.75 188 968831 20.00 ug/1 -0.02 38) Chrysene-dl2 33.82 240 651025 20.00 ug/1 -0.03 44) Perylene-dl2 38.10 264 421823 20.00 ug/1 -0.03

System Monitoring Compounds 37) 2,4-DDD 0.00 235 0 0.00 ug/mL Spiked Amount 5.000 Recovery = 0.00%

Target Compounds Qvalue 2) N-nitroso-dimethyl amine 5.97 74 580512 47.92 ug/1 # 74 3) bis(2-Chloroethyl)ether 11.75 93 874072 43.93 ug/1 94 4) 1,3-Dichlorobenzene 12.24 146 891259 37.63 ug/1 100 5) 1,4-Dichlorobenzene 12.38 146 900494 37.30 ug/1 100 6) 1,2-Dichlorobenzene 12.91 146 828644 36.13 ug/1 100 7) 2,2'-oxybis(1-Chioropropan 13.22 45 1264111 41.96 ug/1 99 8) N-Nitroso-di-n-propylamine 13.63 70 618931 43.48 ug/1 # 88 9) Hexachloroethane 13.75 117 348273 36.04 ug/1 96 11) Nitrobenzene 14.04 77 887619 35.95 ug/1 97 12) 1sophorone 14.69 82 1715298 41.12 ug/1 98 13) bis(2-Chloroethoxy)methane 15.36 93 1056039 40.65 ug/1 98 14) 1,2,4-Trichlorobenzene 15.87 180 714900 34.79 ug/1 98 15) Naphthalene 16.05 128 2324039 36.34 ug/1 99 16) Hexachlorobutadiene 16.58 225 370212 -l0ug/l 99 18) Hexachlorocyclopentadiene 18.77 237 287925 _ .6] ug/1 99 19) 2-Chloronaphthalene 19.55 162 1396279 36.80 ug/1 99 20) Dimethylphthalate 20.66 163 1670231 37.80 ug/1 99 21) 2,6-Dinitrotoluene 20.87 165 398842 39.83 ug/1 88 2 2) Acenaphthylene 20.83 152 2068691 37.75 ug/1 100 23) Acenaphthene 21.40 153 1420565 37.08 ug/1 98 24) 2,4-Dinitrotoluene 22.04 165 528211 41.64 ug/1 # 85 25) Diethylphthalate 22.79 149 1659998 36.15 ug/1 97 26) 4-Chlorophenyl-phenylether 22.93 204 669749 33.88 ug/1 99 27) Fluorene 22.92 166 1466727 35.08 ug/1 100 28) Azobenzen/ 1,2-Diphenylhyd 23.41 77 1788216 37.02 ug/L # 90

(#) = qualifier out of range (m) = manual integration CAL40B.D GCMS0208.M Fri Mar 08 09:03:21 2002 Page 1

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