DEP GCMS data table, Jan-Feb 2002

NYC 9/11 Public Portal Document

Library Search Compound Report

Data File : C:\MSDCHEM\l\5973N\02FEB27\02383.D Vial: 4 Acq On : 27 Feb 2002 1:13 pm Operator: Sample : 508 scan Inst : Instrumen Mise : February 27, 2002 Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\MSDCHEM\1...\HP022102.M (RTE Integrator) Title : 508 scan method Library : C:\DATABASE\WILEY7N.L ********************************************************************* Peak Number 9 9-Azabicyclo[3.3.1]nona-2,6... Concentration Rank 12 R.T. EstConc Area Relative to ISTD R.T. 19.99 0.04 ug/L 25089 Acenaphthene-dl0 18.34 Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 9-Azabicyclo[3.3.1]nona-2,6-dien... 149 C9H11NO 034668-91-2 5 2 N-[3-(Methylamino)propyl]tetrahy... 186 C9H18N202 000000-00-0 4 3 N- (isoxazol-4-yl) -N’ -isopropylth. . . 185 C7H11N30S 122686-04-8 4 4 4-Amino-8-methylimidazo(1,5-a) -1. . . 149 C6H7N5 079681-01-9 4 Abundance Scan 1472 (19.991 min): 02383. D (-) m/ z 71.10 100.00% 71 149

43 5000 185

111/7/111" r1 ' ' ' 1 1 1 1 ‘ 1 1 ' 19.60 19.80 20.00 20.20 20.40 — 0- '11''1' i'11' i ■'111 ■■■■i'■ ■ ■ i ‘ ‘ ■ r ' ■' i''' ■i1‘■1iTi ■ ■ r ■ ■ ■ i1'1 ■ i' ■■■i11 m/z 149.00 99.75% m/z-> 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 Abundance #45299: 9-Azabicyclo[3.3.1 ]nona-2,6-diene-9-carboxaldehyde 149 71 80 104 5000 120 ■ I 1 ' ' 1 I ' ' ' 1 I ' ' 1 1 I ' ' 19.60 19.80 20.00 20.20 20.40 m/ z 43.10 57.59% 92 .

m/z-> 01 "’1111’1111171117111 40 50 60 70 80 H i " 11 ' ■ ■ ■ । ।

90 100 110 120 130 140 150 160 170 180 190 ■ 111 111 ■ ■111'1 ■ ■ i ■1 ■ ■ i1'

Abundance #94962: N-[3-(Methylamino)propyl]tetrahydrofuran-2-carboxamid 71 ■ i ■ ■ ■ 1 i ' ■ I ' ‘ ‘ 1 I 1 ‘ ' I ‘ ' 19.60 19.80 20.00 20.20 20.40 5000 m/z 184.90 40.60%

...................... ........................................................... 186 0- m/z-> 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 Abundance #93685: N-(isoxazol-4-yl)-N'-isopropylthiourea $$ Thiourea... ’ >- ] r rn I 17 1 1 1 1 1 ' 1 1 1 43 19.60 19.80 20.00 20.20 20.40 m/z 185.95 13.37% 185 5000 60

84 . 102 143 । 170 0 TU’0’1’ITTTTITICI’T"EITUTTTITSTTTTT ■1111’ i ■ ■1 11'1 ’ I’’ 'I ' 1 ' 1 I ' 1 ' 1 I ' ■ ' 1 I ' ‘ /z-> 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 19.60 19.80 20.00 20.20 20.40

2383.D HP022102.M Thu Feb 28 08:46:56 2002 Page 11

NYC-WTC_000005000