GCMS DFTPP calibration report, Feb 5 2002

NYC 9/11 Public Portal Document

Library Search Compound Report Data File : C:\MSDCHEM\1\5973N\02FEB05\00004A.D Vial: 3 Acq On 5 Feb 2002 4:36 pm Operator: Sample : 508 scan; re-ext Inst : Instrumen Mise : February 5, 2002 Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\MSDCHEM\1...\HP020702.M (RTE Integrator) Title : 508 scan method Library : C:\DATABASE\WILEY7N.L ********************************************************************* Peak Number 10 2 -(N,N-Dimethylamino-methyl ... Concentration Rank 8 R.T. EstConc Area Relative to ISTD R.T. 18.42 0.11 ug/L 131819 Acenaphthene-dl0 18.35 Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 2-(N,N-Dimethylamino-methylene)-... 153 C9H15NO 000000-00-0 9 2 4-Chloro-lH-imidazo[4,5-c]pyridine 153 C6H4C1N3 000000-00-0 9 3 2H-Azepin-2-one, hexahydro-3 -(2-... 153 C9H15NO 029559-34-0 9 4 6-amino-l-methyl -2-(methylamino)... 154 C6H10N4O 111291-89-5 9 Abundance Scan 1318 (18.421 min): 00004A.D (-) m/z 153.10 100.00% 57 153 40 64

82 5000

49 18.00 18.20 18.40 18.60 18.80 164 m/z 57.10 85.97% 0b n/z-> 30 Abundance 40 50 60 1 ' i ■ ■ ■ ' i 70 1 ■ i ■ ■ ■1111111'11111'11111111111111 90 100 110 120 130 140 150 160 170 80 #51160:2-(N,N-Dimethylamino-methylene)-cyclohexanone 1 ■ i' ‘ ' i ‘ 1

A 153 42 138

5000 82 i ■ ■ । ■ i i > I M ' 1 1 1 1 1 1 1 ' 1 1 1 110 18.00 18.20 18.40 18.60 18.80 96 m/z 40.00 81.20% 124 0b ■ ■ i /z-> 30 40 ■ ■ ।1'1 ■ ।11'111' ■' i 50 60 70 ■ ■ i ' 1 11 ■ ■ ..... 1 90 100 110 120 130 140 150 160 170 80 1.... HI......... Abundance #50621:4-Chloro-1 H-imidazo[4,5-c]pyridine 153 ------- 64 118 18.00 18.20 18,40 18.60 18.80 5000 m/z 44.10 77.79% 52 90 O 11 ,,,,1 1 • i1 1111' 1 1 1 I I ' ■ I ■' i111 ■ i ■1 i ■' ■ ' i1 ■ ■ ■ i ■ ■ ' ■ i PPPTTr miz-> 30 Abundance 40

41 50 60 70 80 90 100 110 120 130 140 150 160 170 #51050:2H-Azepin-2-one, hexahydro-3-(2-propenyl)- (CAS) $... 153 MCAAAALLACA 18.00 18.20 18.40 18.60 18.80 m/z 154.00 77.52% 5000 82 68 96 110 124 138

O- TTTT / I A ■ ' i' • ' ' i ' ■ ■ ■ i 1 ' ■ ■ l ■ ■ TTt ' 1 i 1 • ' i'1 i ■ ' ' ■ i 1 ■ i ■ ■ ■ 1 i 1 1 m/z-> 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 18.00 18.20 18.40 18.60 18.80

00004A.D HP020702.M Thu Feb 21 15:48:48 2002 Page 12

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