DEP GCMS data table, Jan-Feb 2002

NYC 9/11 Public Portal Document Library Search Compound Report Data File : C:\MSDCHEM\1\5973N\02FEB26\02086.D Vial: 3 Acq On : 26 Feb 2002 4:27 pm Operator: Sample : 508 scan Inst : Instrumen Mise : February 2 6, 2002 Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\MSDCHEM\l-..\HP022102.M (RTE Integrator) Title : 508 scan method Library : C:\DATABASE\WILEY7N.L Peak Number 10 2-Propylbenzothiazole $$ Be... Concentration Rank 12 R.T. EstConc Area Relative to ISTD R.T.

19.99 0.03 ug/L 21115 Ac enapht hene-d10 18.34

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 2-Propylbenzothiazole $$ Benzoth... 177 C10H11NS 017229-76-4 9 2 3-METHYLBENZOTRIAZOLE N-OXIDE $$... 149 C7H7N30 026198-26-5 5 3 2-HYDROXYADAMANTANE-1-CARBONITRILE 177 C11H15NO 000000-00-0 5 4 P-NITROSTYRENE $$ Benzene, 1-eth... 149 C8H7NO2 000100-13-0 4 Abundance Scan 1472 (19.991 min): 02086. D (-) m/z 148.90 100.00% 149

71 5000 43 51 162 177 ‘ I 1 11 1 1 1 1 ‘ * | i । ' I* ' 19.60 19.80 20.00 20.20 20.40 0- ■ ■ i ■11 ■ I' ■'111■■111' ■ ■ i ■ ■ ■' i111' i1''11 ■ ■'11 ■ ■' ■ i111 ■ i1 ■’1111 ■ ■ i ■ 1■ m/z 71.10 64.08% m/z-> 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 Abundance #82115:2-Propylbenzothiazole $$ Benzothiazole, 2-propyl-... 149

5000- 19,60 19.80 20.00 20.20 20.40 162 177 m/ z 43.05 43.39% 45 69 108

m/z-> o1 1‘1"11111117111111111111111113 40 50 60 70 80 90 . .....I - 100 110 120 130 140 150 160 170 180 Abundance #45028: 3-METHYLBENZOTRIAZOLE N-OXIDE $$ 1 H-Benzotriazole,... 149 19.60 19.80 20.00 20.20 20.40 5000 51 m/ z 51.00 35.03% 78 65 90 104 119 miz-> 0- .....50I1' 1 60 .40 ■ । *11 * । ■ 70 80 90 100 110 120 130 140 150 160 170 180 111 ' ■ ■ ■ I ■' ■' 11 1

Abundance #82247: 2-HYDROXYADAMANTANE-1-CARBON1TRILE ___ II II 1 1 ' ' 1 ' 1 1 ' ■ ' i ■ ' 1 ' i ' 1 149 19.60 19.80 20.00 20.20 20.40 69 m/z 162.10 31.29% 1 5000 80 130 177

0 1′11111111170-1111′1 ■ ■ i ■ ■ > ■ i ■ ■ ■ ■ i • ■ ■ ■ । ■ —jl......... ... "" । . i i i I 1-1 1 ' i' 1 1 i ■ ■ m/z-> 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 19.60 19.80 20.00 20.20 20.40

02086.D HP022102.M Wed Feb 27 08:35:02 2002 Page 12

NYC-WTC_000004620