DEP GCMS unknown compounds report, Mar 2002

NYC 9/11 Public Portal Document

.Data File : C:\HPCHEM\l\DATA\FEB2502\1802.D Vial: 28 Acq On : 26 Feb 2002 4:31 pm Operator: Sample : gc/ms scan 1/25 Inst : GC/MS 209 Mise : Multiplr: 1.00 MS Integration Params: LSCINT.P

Quant Method : C:\HPCHEM\1\METHODS\GCMS0208.M (RTE Integrator) Title : 209 625/TCLP calibration table Library : C:\DATABASE\NBS75K.L ********************************************************************* Peak Number 2 1-Monolinoleoylglycerol trimet Concentration Rank 5

R.T. EstConc Area Relative to ISTD R.T.

37.46 0.86 ug/1 45940 Perylene-dl2 38.05

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 1-Monolinoleoylglycerol trimethylsi 498 C27H5404Si2 054284-45-6 33 2 Trisiloxane, 1, 1,1,5,5,5-hexamethyl 384 C12H36O4Si5 003555-47-3 32 3 3-1sopropoxy/1,1,1,7,7,7-hexamethyl 576 C18H5207Si7 071579-69-6 28 4 2-Methoxyp nylpyruvic acid. di-TMS 338 C16H2604Si2 000000-00-0 10 Abundance Scan 3532 (37.464 min): 1802.D (-) m/z 73.00 100.00% 3

147 5000 221 281 355 1I 1.. I 191 | — 253 ।J I 429 .00 37.605537.8012 % r m/z37.2014 737.40 m/Z-? 50 100 150 200 250 300 350 400 450 500 550 Abundance #58871: 1-Monolinoleoylglycerol trimethylsilyl ether 73

207 5000- 147 ----- 37.20 37.40 37.60 37.80 34 103 281 m/z 221.05 37.24% ■ 1 i ■ ■ ' ■ । 1 ■ . 395 ...482 ... m/z- 50 100 150 200 250 300 350 400 450 500 550 Abundance 73 147 ■ ■ ■ ■ i ■ ■ ' ' i ‘ ' ■ ' ' I ' ' 281 37.20 37.40 37.6037.80 _ 5000 m/z __ 281.00 25.40%)

207 369 249 ... 338 ..... ... ..... m/z->.... 50 100 150 200 250 300 350 400 450 500 550 Abundance #60503: 3-lsopropoxy-l ,1,1,7,7,7-hexamethyl-3,5,5-tris(trim 73 37.20 37.40 37.60 37.80 m/z 354.9 19.24% 5000 147

221 281 327 I 415 519 561 m/z-> 50 100 150 200 250 300 350 400 450 500 550 37.20 37.40 37.60 37.80

1802.D GCMS0208.M Thu Feb 28 11:52:23 2002 Page 2

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