DEP GCMS unknown compounds report, Mar 2002

NYC 9/11 Public Portal Document

Data File : C:\HPCHEM\1\DATA\FEB2502\1803.D Vial: 29 Acq On : 26 Feb 2002 5:30 pm Operator: Sample : gc/ms scan 1/25 fb Inst : GC/MS 209 Mise Multiplr: 1.00 MS Integration Params: LSCINT.P

Quant Method : C:\HPCHEM\1\METHODS\GCMS0208.M (RTE Integrator) Title : 209 625/TCLP calibration table Library : C:\DATABASE\NBS75K.L

Peak Number 5 2-Oxo-4-phenyl-6-(4-chlorophen Concentration Rank 4

R.T. EstConc Area Relative to ISTD R.T.

45.78 0.52 ug/1 28009 Perylene-d12 38.05

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 2-Oxo-4-phenyl-6-(4-chloropheny1) -1 282 C16H11C1N2O 000000-00-0 10 2 2(1H)-Pyrimidinone,/5-chloro-4,6-di 282 C16H11C1N2O 028567-83-1 10 3 7a, 9c- (Iminoethang/phenanthro [4,5-b 281 C18H19NO2 024695-70-3 9 4 Trisiloxane, 1,1/1,5,5,5-hexamethyl 384 C12H3604Si5 003555-47-3 9 Abundance / Scan 4438 (45.783 min): 1803.D (-) j m/z 73.00... 100.00% 73

147 221 231 5000 44 341 ■ "osr Wy 253 429 i ..................................... ................ ■ 45.40 45.60 45.80 46.00 46.20

m/z-> ....... " ।111' i"1' i1i" " r " ‘ ।" "i mmgmgmmgm m/z 147.00M 64.08% I “' * 111" 11' ‘11' ‘1 ‘ I' 40 60 80 100120140 160 180 200 220 240 260 280 300 320 340 360 380 400 420 Abundance #39756:2-0x0-4-phenyl-6-(4-chloropheny!)-1,2-dihydropyrimi . / W

5000- 45.40 45.60 45.80 46.00 46.20 m/z 221.05 55.62% ...12123141 175 .. ....... . ..,, i|............................ i m/z-> 40 60 80 100120140160180 200 220 240 260 280 300 320 340 360 380 400 420 Abundance 281 A [ 45.40 45.60 45.80 46.00 46.20 5000 I m/z 281.00 51.46% 77 104 204 247

m/z-> „ 40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 340 360 380 400 420 . "wW Myin Abundance #72283: 7a,9c-(minoethano)phenanthro[4,5-bed]furan, 4a.alp ‘I l ' ' ■ ‘ I ‘ 281 45.40 45.60 45.80 46.00 46.20 " 282.00 37.17% 5000 152 253

m/z-> " i “ " i' “' 11"1111" I" " I" 181 -HHHHHH 209 1111101111111110111121110—11—07110117 40 60 80 100 120140 160180 200 220 240 260 280 300 320 340 360 380 400 420 | . , I 1 1 1 ' ' 1 1 1 ' ‘ 1 1 1 45.40 45.60 45.80 46.00 46.20 ' 1 11 ' ' I '

1803 .D GCMS0208.M Thu Feb 28 11:54:24 2002 Page 5

NYC-WTC_000003773