VOC analysis results, sample AE10890, May 2002

NYC 9/11 Public Portal Document Quantitation Report (Not Reviewed)

Data File : C:\HPCHEM\l\DATA\02may07\0507C10.D Vial: 2 Acq On : 7 May 2002 10:35 am Operator: 201-wb Sample : cal 10 Inst : GC/MS Ins Mise : May 6, 2002 Multiplr: 1.00 MS Integration Params: RTEINT.P Quant Time: May 7 11:14 2002 Quant Results File: HP042202.RES

Quant Method : C:\HPCHEM\1\METHODS\HP042202.M (RTE Integrator) Title : VOCs BY EPA METHOD 524 Last Update : Mon May 06 11:52:45 2002 Response via : Initial Calibration DataAcq Meth : HP042202

Internal Standards R.T. Qlon Response Cone Units Dev(Min)

1) 1,4-DIFLUOROBENZENE 15.10 114 1504681 5.00 ug/L 0.02 24) CHLOROBENZENE-D5 21.76 117 1429312 5.00 ug/L 0.02 52) 1,4-DICHLOROBENZENE-D4 26.95 152 713070 5.00 ug/L 0.02

System Monitoring Compounds 2) 1,2-DICHLOROETHANE-D4 14.34 65 652351 4.74 ug/L 0.02 Spiked Amount 5.000 Recovery = 94.80% 3) 4-BROMOFLUOROBENZENE 24.35 174 579393 5.21 ug/L 0.02 Spiked Amount 5.000 Recovery = 104.20% 25) TOLUENE-D8 18.46 98 1798742 4.87 ug/L 0.02 Spiked Amount 5.000 Recovery = 97.40%

Target Compounds Qvalue 4) DICHLORODIFLUOROMETHANE 4.86 85 662310 11.23 ug/L 99 5) CHLOROMETHANE 5.45 50 649602 8.57 ug/L 94 6) VINYL CHLORIDE 5.60 62 539452 13.01 ug/L 98 7) BROMOMETHANE 6.58 94 466875 11.83 ug/L. 98 8) CHLOROETHANE 6.71 64 470066 10.95 ug/L 95 9) TRICHLOROFLUOROMETHANE 7.28 101 937621 12.61 ug/L 97 11) 1,1,2-Trichloro-l,2,2-trif 8.17 101 509583 10.29 ug/L 98 12) ACETONE 8.24 43 296465 23.16 ug/L 96 13) 1,1-DICHLOROETHENE 8.60 61 1071747 8.59 ug/L 98 14) METHYLENE CHLORIDE 9.60 49 854776 7.25 ug/L 92 ■15) METHYL TERT BUTYL ETHER 9.91 73 567553 6.96 ug/L 95 16) TRANS-1,2-DICHLOROETHENE 10.27 61 1036870 8.05 ug/L 92 17) 1,1-DICHLOROETHANE 11.15 63 1133288 7.94 ug/L 96 18) 2-BUTANONE (MEK) 11.99 43 329011 26.43 ug/L 92 19) 2,2-DICHLOROPROPANE 12.38 77 872122 8.45 ug/L 99 20) CIS-1,2-DICHLOROETHENE 12.46 96 652259 9.15 ug/L 93 21) CHLOROFORM 12.80 83 1252681 9.25 ug/L 99 22) BROMOCHLOROMETHANE 13.20 49 467167 7.48 ug/L 74 23) 1,2-DICHLOROETHANE 14.52 62 895583 8.59 ug/L 98 26) 1,1,1-TRICHLOROETHANE 13.71 97 986011 9.40 ug/L 99 27) 1,1-DICHLOROPROPENE 14.03 75 993992 9.13 ug/L 98 28) CARBON TETRACHLORIDE 14.28 117 886851 10.03 ug/L 97 29) BENZENE 14.63 78 2113656 8.43 ug/L 98 30) TRICHLOROETHENE 15.90 95 738115 9.17 ug/L 95 31) 1,2-DICHLOROPROPANE 16.26 63 537968 7.50 ug/L 98 32) DIBROMOMETHANE 16.92 174 284592 9.23 ug/L 93 33) BROMODICHLOROMETHANE 16.77 83 835760 9.07 ug/L 98 34) 2-CHLOROETHYL VINYL ETHER 17.26 63 151217 7.37 ug/L 89 35) METHYL ISO-BUTYL KETONE 17.33 58 272064 29.48 ug/L 99 36) CIS-1,3-DICHLOROPROPENE 17.88 75 797811 8.56 ug/L 98 37) TOLUENE 18.63 91 2216374 8.74 ug/L 100 38) TRANS-1,3-DICHLOROPROPENE 18.90 75 577185 8.59 ug/L 98 39) 1,1,2-TRICHLOROETHANE 19.29 97 338421 8.57 ug/L 97 40) TETRACHLOROETHENE 20.07 166 675848 9.66 ug/L 99 41) 1,3-DICHLOROPROPANE 19.82 76 662001 8.33 ug/L 99 42) DIBROMOCHLOROMETHANE 20.52 129 444167 9.75 ug/L 98 43) 1,2-DIBROMOETHANE 20.98 107 346440 8.63 ug/L 95 44) CHLOROBENZENE 21.84 112 1400767 9.17 ug/L 94 45) 1,1,1,2-TETRACHLOROETHANE 21.89 131 536687 9.66 ug/L 98 46) 2-HEXANONE 19.19 43 489191 27.79 ug/L 97 47) ETHYLBENZENE 21.88 91 2653948 9.21 ug/L 100

(#) = qualifier out of range (m) = manual integration 0507C10.D HP042202.M Tue May 07 11:14:28 2002 Page 1

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