GCMS calibration results, April 2002

NYC 9/11 Public Portal Document

Quantitation Report (Not Reviewed)

Data File : C:\MSDCHEM\l\DATA\041802VC100B-d8.D Vial: 19 Acq On : 19 Apr 2002 12:24 am Operator: Bohlk Sample : ClOO Inst Instrumen Mise : Multiplr: 1.00 MS Integration Params: BENZO.P Quant Time: Apr 19 08:27:15 2002 Quant Results File: 5080402BBC.RES

Quant Method : C:\MSDCHEM\l\5973N\5080402BBC.M (RTE Integrator) Title : Quantitation For Method 508gcscan Last Update : Tue Apr 16 18:27:45 2002 Response via : Initial Calibration DataAcq Meth : 508SCAN

Internal Standards R.T. Qlon Response Cone Units Dev(Min)

1) 1,4-Dichlorobenzene-d4 9.42 152 488057 40.00 ug/L 0.00 10) Naphthalene-d8 12.90 136 2051229 40.00 ug/L 0.01 17) Acenaphthene-dlO 18.00 164 1128310 40.00 ug/L 0.02 30) Phenanthrene-dlO 22.35 188 1639891 40.00 ug/L 0.01 39) Chrysene-dl2 30.19 240 1208364 40.00 ug/L 0.04 45) Perylene-dl2 . 34.04 264 799394 40.00 ug/L 0.03

System Monitoring Compounds 28) TCMX (SURR) 19.97 244 42946 9.54 ug/L 0.02 Spiked Amount 10.000 Recovery = 95.40% 38) 2,4-DDD (SURR) 0.00 235 0 0.00 ug/L Spiked Amount 10.000 Recovery 0.00% I - 2^* Target Compounds Qvalue 2) N-nitroso-dimethyl amine 3.45 74 2932831 207.80 ug/L 88 3) bis(2-chloroethyl) ether 8.87 93 4143939 200.25 ug/L 81 4) 1,3. - Dichlorobenze 9.25 146 3148581 186.22 ug/L 98 5) 1,4 - Dichlorobenzene 9.47 146 3309898 182.88 ug/L 99 6) 1,2 - Dichlorobenzene 9.84 146 2896460 195.79 ug/L 99 7) 2,2 ' - oxybis (1-Chloropr 10.31 45 5800474 187.90 ug/L 96 8) N-Nitroso-di-n-propylamine 10.68 70 2905286 196.96 ug/L ’ 94 9) Hexachloroethane 10.73 117 1424986 177.03 ug/L 99 11) Nitrobenzene 11.01 77 4235474 212.78 ug/L 97 12) Isophorone 11.72 82 7443410 187.96 ug/L 99 13) bis(2-Chloroethoxy) methan 12.46 93 4648239 192.41 ug/L 99 14) 1,2,4-Trichlorobenzene 12.79 180 2399308 180.80 ug/L 99 15) Naphthalene 12.97 128 8612201 171.69 ug/L 100 16) Hexachlorobutadiene 13.41 225 1194139 186.69 ug/L 96 18) Hexachlorocyclopentadiene 15.48 237 1227045 232.38 ug/L 96 19) 2-chloronaphthalene 16.39 162 4581051 200.70 ug/L 96 20) Dimethylphthalate 17.50 163 6254931 192.75 ug/L 99 21) 2,6-Dinitrotoluene 17.63 165 1350841 213.70 ug/L 95 22) Acenaphthylene 17.58 152 7926349 189.95 ug/L 99 23) Acenaphthene 18.11 153 4617436 174.94 ug/L 99 24) 2,4-Dinitrotoluene 18.77 165 1679072 220.52 ug/L 97 25) Diethylphthalate 19.63 149 4624900 171.66 ug/L 99 26) 4-Chlorophenyl-phenyl ethe 19.78 204 2683183 180.12 ug/L 98 27) Fluorene 19.65 166 5202043 170.85 ug/L 99 29) Azobenzen/ 1,2-Diphenylhyd 20.24 77 8287898 176.89 ug/L 97 31) N-Nitrosodiphenylamine 20.16 169 2931949 167.69 ug/L 99 32) 4-Bromophenyl-phenyl ether 21.21 248 1422940 187.53 ug/L 99 . 33) Hexachlorobenzene 21.23 284 1310595 184.79 ug/L 99 34) Phenanthrene 22.44 178 7926371 174.42 ug/L 99 35) Anthracene 22.60 178 8307570 179.21 ug/L 99 36) Di-n-butylphthalate 24.54 149 9462048 182.08 ug/L 100 37) Fluoranthene 25.95 202 9257885 192.09 ug/L 96 40) Pyrene 26.58 202 8862110 194.48 ug/L 97 41) Butylbenzylphthalate 28.94 149 4287935 203.70 ug/L 91 42) Benzo (a) antracene 30.17 228 7550817 205.17 ug/L 99 43) Bis (2-ethylhexyl) phthala 30.79 149 5721667 191.39 ug/L 99 44) Chrysene 30.28 228 7021309 192.74 ug/L 99

(#) = qualifier out of range (m) = manual integration C100B418.D 5080402BBC.M Fri Apr 19 08:27:42 2002 Page 1

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