GCMS calibration results, April 2002

NYC 9/11 Public Portal Document

Quantitation Report (Not Reviewed)

.• Data File : C:\MSDCHEM\l\DATA\041002\ 0410.D Vial: 6 Acq On : 10 Apr 2002 7:51 pm Operator: Bohllc Sample : C25 Inst : Instrumen Mise Multiplr: 1.00 MS Integration Params: BENZO.P Quant Time: Apr 15 15:54:00 2002 Quant Results File: 5080402BB.RES

Quant Method : C:\MSDCHEM\l\5973N\5080402BB.M (RTE Integrator) Title : Quantitation For Method 508gcscan Last Update : Mon Apr 15 15:51:29 2002 Response via : Initial Calibration DataAcq Meth : 508SCAN

Internal Standards R.T. Qlon Response Cone Units Dev(Min)

1) 1,4-Dichlorobenzene-d4 9.41 152 751764 40.00 ug/L 0.00 10) Naphthalene-d8 12.89 136 3119258 40.00 ug/L 0.00 17) Acenaphthene-dlO 18.00 164 1715190 40.00 ug/L 0.00 30) Phenanthrene-dlO 22.35 188 2451618 40.00 ug/L 0.00 39) Chrysene-dl2 30.16 240 1626405 40.00 ug/L 0.00 45) Perylene-dl2 34.03 264 1018329 40.00 ug/L 0.00

System Monitoring Compounds 28) TCMX (SURR) 0.00 244 0 0.00 ug/L Spilled Amount 5.000 Recovery = 0.00% 38) 2,4-DDD (SURR) 27.27 235 12558 9.74 ug/L 0.00 Spilced Amount 5.000 Recovery = 194.80%

Target Compounds Qvalue 2) N-nitroso-dimethyl amine 3.44 74 627710 44.49 ug/L 86 3) bis(2-chloroethyl) ether 8.86 93 957744 46.28 ug/L 98 4) 1,3 - Dichlorobenze 9.25 146 858610 45.66 ug/L 98 5)'1,4 - Dichlorobenzene 9.46 146 841647 45.35 ug/L 99 6) 1,2 - Dichlorobenzene 9.84 146 780433 45.33 ug/L 97 7) 2,2-' - oxybis (1-Chloropr 10.31 45 1414328 45.26 ug/L 98 8) N-Nitroso-di-n-propylamine 10.65 70 739439 49.95 ug/L 95 9) Hexachloroethane 10.72 117 343034 48.00 ug/L 92 11) Nitrobenzene 10.98 77 1114723 45.72 ug/L 98 12) Isophorone 11.70 82 1967162 45.06 ug/L 98 13) bis(2-Chloroethoxy) methan 12.44 93 1234758 46.84 ug/L 100 14) 1,2,4-Trichlorobenzene 12.77 180 619546 45.60 ug/L 99 15) Naphthalene 12.94 128 2494142 45.94 ug/L 99 16) Hexachlorobutadiene 13.40 225 311192 46.01 ug/L 97 18) Hexachlorocyclopentadiene 15.46 237 196313 41.76 ug/L 99 19) 2-chloronaphthalene 16.37 162 1348344 45.72 ug/L 97 20) Dimethylphthalate 17.47 163 1569961 46.00 ug/L 98 21) 2,6-Dinitrotoluene 17.57 165 337164 45.39 ug/L 97 22) Acenaphthylene 17.55 152 1922233 48.31 ug/L 99 23) Acenaphthene 18.09 153 1327406 46.21 ug/L 99 24) 2,4-Dinitrotoluene 18.73 165 472606 47.57 ug/L 96 25) Diethylphthalate 19.61 149 1340563 45.64 ug/L 99 26) 4-Chlorophenyl-phenyl ethe 19.75 204 691021 45.52 ug/L 99 27) Fluorene 19.62 166 1508266 45.59 ug/L 97 29) Azobenzen/ 1,2-Diphenylhyd 20.21 77 2291475 45.74 ug/L 95 31) N-Nitrosodiphenylamine 20.14 169 1013238 46.50 ug/L 99 32) 4-Bromophenyl-phenyl ether 21.18 248 342339 45.82 ug/L 95 33) Hexachlorobenzene " 21.20 284 337116 46.46 ug/L 84 34) Phenanthrene 22.42 178 2070752 45.86 ug/L 100 35) Anthracene 22.56 178 2009491 46.36 ug/L 100 36) Di-n-butylphthalate 24.51 149 2443681 47.24 ug/L 99 37) Fluoranthene 25.91 202 2125054 46.28 ug/L 87 40) Pyrene 26.53 202 2137491 44.88 ug/L 89 41) Butylbenzylphthalate 28.90 149 1013585 46.15 ug/L 89 42) Benzo (a) antracene 30.12 228 1423953 43.73 ug/L 99 43) Bis (2-ethylhexyl) phthala 30.77 149 1389172 47.45 ug/L 99 44) Chrysene 30.22 228 1404698 44.46 ug/L 99

(#) = qualifier out of range (m) = manual integration C25B0410.D 5080402BB.M Mon Apr 15 15:54:18 2002 Page 1

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