GCMS Method 525.2 calibration results, Mar 2002

NYC 9/11 Public Portal Document

Quantitation Rewrt (QT Reviewed)

Data File : C:\HPCHEM\l\DATA\MAR2702\ LD Vial: 2 Acq On : 27 Mar 2002 2:38 pm Operator: Sample Inst : GC/MS 209 Mise Multiplr: 1.00 MS Integration Params: GOOFY.P Quant Time: Mar 29 12:24 2002 Quant Results File: GCMS0308.RES

Quant Method : C:\HPCHEM\1\METHODS\GCMS0308.M (RTE Integrator) Title : 209 625/TCLP calibration table Last Update : Fri Mar 29 10:31:28 2002 Response via : Initial Calibration DataAcq Meth : GCMS0308

Internal Standards R.T. Qlon Response Cone Units Dev(Min)

1) 1,4-Dichlorobenzene-d4 12.26 152 714096 20.00 ug/1 -0.09 10) Naphthalene-d8 15.90 136 2919166 20.00 ug/1 -0.09 17) Acenaphthene-dlO 21.21 164 1607999 20.00 ug/1 -0.10 29) Phenanthrene-dlO 25.65 188 2472223 20.00 ug/1 -0.11 38) Chrysene-dl2 33.72 240 1480012 20.00 ug/1 -0.12 44) Perylene-dl2 37.95 264 794141 20.00 ug/1 -0.17

System Monitoring Compounds 37) 2,4-DDD 0.00 235 0 0.00 ug/mL Spiked Amount 5.000 Recovery = 0.00%

Target Compounds 2) N-nitroso-dimethyl amine 5.91 74 927716 38.30 ug/1 # 70 3) bis(2-Chloroethyl)ether 11.68 93 1576980 40.42 ug/1 90 4) 1,3-Dichlorobenzene 12.16 146 1644282 40.79 ug/1 100 5) 1,4-Dichiorobenzene 12.30 146 1658784 41.06 ug/1 99 6) 1,2-Dichlorobenzene 12.83 146 1555519 41.27 ug/1 99 7) 2,2'-oxybis(1-Chloropropan 13.14 45 2107172 38.38 ug/1 98 8) N-Nitroso-di-n-propylamine 13.56 70 1049667 41.36 ug/1 # 86 9) Hexachloroethane 13.66 117 608895 40.32 ug/1 95 11) Nitrobenzene 13.96 77 1547880 38.79 ug/1 91 12) Isophorone 14.61 82 2963065 39.15 ug/1 99 13) bis(2-Chloroethoxy)methane 15.29 93 1962824 39.63 ug/1 98 14) 1,2,4-Trichlorobenzene 15.78 180 1476732 43.10 ug/1 97 15) Naphthalene 15.97 128 4492069 41.63 ug/1 99 16) Hexachlorobutadiene 16.49 225 758411 44.39 ug/1 99 18) Hexachlorocyclopentadiene 18.69 237 571373 52.47 ug/1 99 19) 2-Chloronaphthalene 19.47 162 2829353 40.98 ug/1 96 20) Dimethylphthalate 20.57 163 3290986 40.67 ug/1 99 21) 2,6-Dinitrotoluene 20.79 165 804050 40.94 ug/1 # 79 22) Acenaphthylene 20.74 152 3989691 40.42 ug/1 99 2 3) Acenaphthene 21.31 153 2785480 40.38 ug/1 99 24) 2,4-Dinitrotoluene 21.95 165 1025448 39.02 ug/1 # 77 25) Diethylphthalate 22.71 149 3092695 39.37 ug/1 95 26) 4-Chlorophenyl-phenylether 22.84 204 1419529 42.20 ug/1 92 27) Fluorene 22.83 166 2973512 40.76 ug/1 100 28) Azobenzen/ 1,2-Diphenylhyd 23.32 77 2925170 34.74 ug/L # 83

{#) = qualifier out of range (m) = manual integration CAL40.D GCMS0308.M Fri Mar 29 12:27:15 2002 Page 1

NYC-WTC_000058172