GCMS results for sample AE00314, Jan 24 2002

NYC 9/11 Public Portal Document

Library Search Compound Report Data File : C:\MSDCHEM\1\5973N\02JAN14\00314.D Vial: 3 Acq On : 14 Jan 2002 12:09 pm Operator: Sample : 508 scan Inst : Instrumen Mise : January 14, 2002 Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\MSDCHEM\1...\SCAN508.M (RTE Integrator) Title : 508 scan method Library : C:\DATABASE\WILEY7N.L ********************************************************************* Peak Number 4 Butenol, methyl- Concentration Rank 4

R.T. EstConc Area Relative to ISTD R.T. 5.01 0.16 ug/L 56647 1,4-Dichlorobenzene-d4 9.71 Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 Butenol, methyl- 86 C5H10O 060766-00-9 78 2 3-Buten-2-ol, 2-methyl- 86 C5H10O 000115-18-4 74 3 Butane, 2-bromo-2-methyl- $$ ter... 150 C5HllBr 000507-36-8 45 4 Butane, 2,2-dimethyl- 86 C6H14 000075-83-2 42 Abundance Scan 143 (5.006 min): 00314.D (-) m/ z 71.10 100.00% 43 71

5000

53 59 M ... 4.60 4.80 5.00 5.20 5.40

miz-> llaadponi/ O' • । 1 1 1 ' । 1 * ' • । 1 10 20 30 40 50 60 70 80 86.......................................... 90 100 110 120 130 m/z 43.10 96.04% Abundance #4093: Butenol, methyl- 43 71

5000 59 Nw / AAA 27 4.60 4.80 5.00 5.20 5.40 15 m/z 41.10 60.47% 53 0— I —1 ' I ' ' 86 m/z-> 10 20 30 40 50 60 70> 80 90 100 110 120 130 Abundance #4083: 3-Buten-2-ol, 2-methyl- 71 43 M A 4 60 4.80 5.00 5.20 5.40 5000 m/z 59.10 36.10% 59 27 53

n/z-> ............. 11 37 01 1 ■ i ■ ■ ■ ■ i ■ ■ ■ 1 i ■ ■ ■ ■ i ' 10 20 30 40 ndl -86---------------- 50 60 — 70I 80 90 100 110 120 130 Abundance #45652: Butane, 2-bromo-2-methyl- $$ tert-Amyl bromide $$ ... 43 71 unie 4.60 -A-A— 4.80 5.00 5.20 5.40 m/z 69.10 34.89% 5000 27 55

m/z-> 15 0 >■i>■ ■ ■। • 10 20 +341 30 40 1 1 1 11 1 .......... 1 । 1 50 60 70 80 121 90 100 110 120 130 4.60 4.80 5.00 5.20 5.40

)0314.D SCAN508.M Tue Jan 15' 08:47:51 2002 Page 6

NYC-WTC_000051373