GCMS analysis results for sample AE00105, Feb 2002

NYC 9/11 Public Portal Document Library Search Compound Report Data File : C : \MSDCHEM\1\5973N\02JAN25\00105 . D Vial: 3 ’ Acq On : 25 Jan 2002 11:49 am Operator: Sample : 508 scan Inst : Instrumen Mise : January 25, 2002 Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\MSDCHEM\1...\SCAN508.M (RTE Integrator) Title : 508 scan method Library : C:\DATABASE\WILEY7N.L Peak Number 5 3-Buten-2-ol, 2-methyl- (CA... Concentration Rank 4 R.T. EstConc Area Relative to ISTD R.T. 5.01 0.30 ug/L 128496 1,4-Dichlorobenzene-d4 9.71 Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 3-Buten-2-ol , 2-methyl- (CAS) $$... 86 C5H10O 000115-18-4 72 2 Butenol, methyl- 86 C5H10O 060766-00-9 64 3 3-Buten-2-ol, 2-methyl- 86 C5H10O 000115-18-4 56 4 2-METHYLBUT-3-EN-2-OL 86 C5H10O 000000-00-0 53 Abundance Scan 143 (5.006 min): 00105.D (-) m/z 43.10 100.00% 48 71 A 5000 55 59 39 ------ 511 . 67 1 85 4 60 4.80 5.00 5.20 5.40 l11" i ■ ■ ■ ■ i ■ ■ ■ ■ r ■ ■' i — P11PPPPPTTTTT m/z 71.10 97.52% n/z-> 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 Abundance #4088:3-Buten-2-ol, 2-methyl- (CAS) $$ 2-Methyl-3-buten-2... 7

5000 1/ 4.80 59 4.60 5.00 5.20 5.40 m/ z 41.05 54.05% 53

m/z-> ++ 4— 67+ , 85 i " " r ■ " i ■ ’ ■ ■ i ■ ’ " i1J " i'k " r ■ " i 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 1" r ■ " r " ■ r " ' i " " i

Abundance #4093: Butenol, methyl- 43 71 AA A

4.60 4.80 5.00 5 20 5.40 5000 59 m/z 69.10 36.83% 27 15 31 53

n/z--> i'' ■ ■ i .67 Ppn 86 i ■■ ■ ■ i

5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 I • ■ l< | ■ 111" r "■i" "i

Abundance #4084:3-Buten-2-ol, 2-methyl- 71 .......4.80Punily5.00A 520 5.40 4.60 43 m/z 59•10 30.82%

5000 59

27 53 — . 67 86 mmmPP olajund....... ........ 1 ■■ I■"■l■■■■l1" ■ l ■ ■ ■ ■ l — A n/z-> 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 4.60 4.80 5.00 5.20 5.40

00105.D SCAN508.M Mon Jan 28 09:49:47 2002 Page 7

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