GCMS analysis results for sample AD31645, Jan 25 2002

NYC 9/11 Public Portal Document

Library Search Compound Report • Data File : C: \MSDCHEM\1\5973N\02JAN22\31645.D Vial: 1 Acq On : 22 Jan 2002 12:12 pm Operator: Sample : 508 scan Inst : Instrumen Mise : January 22, 2002 Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\MSDCHEM\1...\SCAN508.M (RTE Integrator) Title : 508 scan method Library : C:\DATABASE\WILEY7N.L ********************************************************************* Peak Number 11 Cyclic octaatomic sulfur $$... Concentration Rank 1

R.T. EstConc Area Relative to ISTD R.T.

26.01 1.18 ug/L 677403 Phenanthrene-dl0 22.63

Hit# of 5 Tentative ID MW MolForm CAS# Qual 1 Cyclic octaatomic sulfur $$ Sulf... 256 S8 010544-50-0 95 2 Sulfur, mol. (S8) (CAS) $$ OCTA-... 256 S8 010544-50-0 95 3 Sulfur, mol. (S8) (CAS) $$ OCTA-... 256 S8 010544-50-0 95 4 Cyclic octaatomic sulfur 256 S8 010544-50-0 94 Abundance Scan 1983 (26.014 min): 31645.D (-) m/z 64.00 100.00% 64

128 256 5000 160

96 192

m/z-> 44 ■ ' i ■ 1 ■ ■ i 40 60 J 76 ■ • ■ i ■ ■ 80 I | । 224 —IIa—B—nnBnnnBon 100 120 140 160 180 200 220 240 260 1 25.60 25.80 26.00 26.20 26.40 m/z 127.90 54.10% Abundance #195805: Cyclic octaatomic sulfur $$ Sulfur, mol. (S8) $$... 64 256 128 160 ) 5000 192 25.60 25.80 26.00 26.20 26.40 96 224 m/z 255.80 49.66% 34 | | 1 I • ■ i ■ ■ ■ ■ i ■ ■ ■ i ■ miz-> 40 60 100 120 140 160 180 200 220 240 80 260 Abundance #195807: Sulfur, mol. (S8) (CAS) $$ OCTA-SULFUR $$ S8 $$ S... 64 .................... ) ( । ‘ । ■ ■ ■ ■ । ■ ■ i ■ ■ ■ ■ i ■ ■ 25.60 25.80 26.00 26.20 26.40 5000 m/z 159.90 46.75% 128 256 96 160 192

miz-> 34 48 • • 1*1** 40 60 — 80 i । 224 ■ i ■ ■ ■ 1 i ■ 1 ' 1 i 1 ■ 100 120 140 160 180 200 220 240 260 I— Abundance #195806: Sulfur, mol. (S8) (CAS) $$ OCTA-SULFUR $$ S8 $$ S... ........................) \ i ■ ■ ■ ■ i • ■ ■ ■ i ■ ■ ■ ■ i ■ ■ ■ ■ i ■ ■ 64 256 25.60 25.80 26.00 26.20 26.40 m/z 191.80 27.39% 160 128 5000

96 192 224 34 .................... / ...................... TTnnmgt I ■ 1____ 1 i * 1 i ■ ■ * 1 t 1 11 i ■ 1 1 ■ f I'1 1 1 i 1 1 1 i ■ i ■ ■ ■ 1 i ■ • ■ • i • • • • i ■ ■ ■ ■ i • ■ m/z—> 40 60 80 100 120 140 160 180 200 220 240 260 25.60 25.80 26.00 26.20 26.40

31645.D SCAN508.M Thu Jan 24 13:50:36 2002 Page 13

NYC-WTC_000050238