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GCMS blank analysis for sample AE00005, Feb 8 2002

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Blank analysis report for GCMS testing of sample AE00005 showing non-detectable levels of target compounds.

NYC-WTC_000050079–000050087

Folder label: “GCMS X 1/3/02 A 1/24/02

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NYC 9/11 Public Portal Document

Library Search Compound Report

Data File C:\HPCHEM\1\DATA\JAN2 4 02\LB.D Vial: 3 Acq On 24’Jan 2002 2:01 pm Operator: 209 GALOS Sample GC/MS SCAN 1/3 Inst : GC/MS 209 Mise Multiplr: 1.00 MS Integration Params: LSCINT.P

Quant Method C:\HPCHEM\1\METHODS\GCMS0103.M (RTE Integrator) Title 209 625/TCLP calibration table Library C:\DATABASE\NBS75K.L ********************************************************************* Peak Number 2 Cyclopentasiloxane, decamethyl Concentration Rank 2

R.T. EstConc Area Relative to ISTD R.T.

14.13 0.93 ug/1 295096 Naphthalene-d8 15.08

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 Cyclopentasiloxane, decamethyl- 370 C10H3005Si5 000541-02-6 50 2 N-(Trifluoroacetyl)-0,0',0''-tris(t 481 C19H34F3NO4Si3 000000-00-0 43 3 Benzoic acid, 2-[(trimethylsilyl )ox 282 C13H2203Si2 003789-85-3 37 4 Benzoic 'acid, 2,5-bis(trimethylsilo 370 C16H30O4Si3 003618-20-0 37 Abundance Scan 990 (14.130 min): LB.D (-) m/z 73.00 100.00% 73

5000 267 355 45 13.80 14.00 14.20 14.40 1 103 133154 193 223 . - —T———mmmor 323 . m/z 266.90 34.48% miz-> 50 100 150 200 250 300 350 400 450 Abundance #51266: Cyclopentasiloxane, decamethyl- 73 355 267 \ 5000- TT 13.80 14.00 14.20 14.40 m/z 355.05 25.96% .............................. 207 323 | b m/z-> 50 100 150 200 250 300 350 400 450 Abundance #58326: N-{Trifluoroacety!)-0.O,0"-tris(trmneihylsilyh)no 73 355 13.80 14.00 14.20 14.40 5000 m/z 267.90 9.61%

45 ■ 126147 193 265 ....... I 376 ........ 481 m/z-> 50 100 150 200 250 300 350 400 450 Abundance #72298: Benzoic acid, 2-[(trimethylsilyl)oxy]-, trimethylsi \ ‘I 73 267 13.80 14.00 14.20 14.40 m/z 356.05 9.00% ! 5000-

135 47 TT 7I 123 ( 233 ......... /.......... m/z~> 50 100 150 200 250 300 350 400 450 13.80 14.00 14.20 14.40

LB.D GCMS0208.M Fri Feb 08 13:45:53 2002 Page 2

NYC-WTC_000050086

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NYC-WTC_000050086Source: NYC Law Department, mirrored locally

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GCMS blank analysis report, Feb 2002 · Box DEP Box 12

NYC-WTC_000005159

Blank sample analysis report confirming no contamination above method detection limits for target compounds analyzed on February 1, 2002.

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