GCMS results for sample AE09092, April 30, 2002

NYC 9/11 Public Portal Document

Data File : C:\HPCHEM\1\DATA\APR2502\9092 .D Vial: 23 Acq On : 26 Apr 2002 1:42 pm Operator: Sample : re-inject Inst : 209 Mise Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\HPCHEM\1\METHODS\GCMS0412.M (RTE Integrator) Title : 209 625/TCLP calibration table Library : C:\DATABASE\NBS75K.L ********************************************************************* Peak Number 1 Toluene Concentration Rank 4

R.T. EstConc Area Relative to ISTD R.T.

6.36 0.53 ug/1 56260 1,4-Dichlorobenzene-d4 12.21

Hit# of 5 Tentative ID MW MolForm CAS# Qual 1 Toluene 92 C7H8 000108-88-3(91 2 2,5- Norbornadi ene 92 C7H8 000121-46-0 50 3 1,3,5-Cycloheptatriene 92 C7H8 000544-25-2 38 4 Cyclobutene, 2-propenylidene- 92 C7H8 052097-85-5 37 Abundance Scan 144 (6.365 min): 9092.D (-) m/z 91.00 100.00% 91

5000

345 50 61/65 77 84 , 6.00 6.20 6.40 6.60 6.80 TTIWWTIWTTTTTTHNPINPTTTI 1 ‘ 1 1 1 1 ‘ 1 1 1 m/z 92.00 60.41% miz-> 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 Abundance #63030: Toluene 91

5000 • i ■ ■ ■ ' i ■ • ■ • i ' ‘ ■ ■ i ' 6.00 6.20 6.40 6.60 6.80 m/ z 39.05 11.64% " i■•i•‘i “ ■•i‘•1•i “ •'11'■■I‘ 45 51 61 65 ‘ I “ ■11'1 ‘' I' ■ • ■ i' “ ' i ■ • • ■ i ■ ■ • ■ i ■ 11 Ianiipin miz-> 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 Abundance #63032:2,5-Norbornadiene 91

6.00 6.20 6.60 6.80 5000 66 m/ z 64.95 10.36%

...... 27.......... 41...... 51 mM4.mmmm+ HT]o " | “ 1 I ' । TTriru . | > > > I | > l . I | . 1 1 ! | J t . I J i miz-> 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 Abundance #63036:1,3,5-Cycloheptatriene ............. .. 91 6.00 6.20 6.40 6.60 6.80 m/z 62.9.5 7.92% 5000

65 27 38 > I 1 . I I I ! . I rr| 1 I I >| >1 1 M, 46.5144614 • i" " i " ‘' i ■ ‘■ i “'11 " i ‘“ i ■' iz—> 20 25 30 35 404550556065 70 75 80 85 90 95 100 6.00 6.20 6.40 6.60 6.80

9092.D GCMS0412.M Fri Apr 26 14:50:23 2002 Page 1

NYC-WTC_000049503