GCMS reference data for sample AE08971, April 2002

NYC 9/11 Public Portal Document Quantitation Report (QT Reviewed)

Data File : C:\HPCHEM\1\DATA\APR25O2\REFA1.D Vial: 15 Acq On : 26 Apr 2002 2:15 am Operator : Sample : re-inject Inst : 209 Mise Multiplr: 1.00 MS Integration Params: GOOFY.P Quant Time: Apr 26 9:29 2002 Quant Results File: GCMS0412.RES

Quant Method : C:\HPCHEM\1\METHODS\GCMS0412.M (RTE Integrator) Title : 209 625/TCLP calibration table Last Update : Thu Apr 25 15:21:43 2002 Response via : Initial Calibration DataAcq Meth :. GCMS0412

Internal Standards R.T. Qlon Response Cone Units Dev(Min)

1) l,4-Dichlorobenzene-d4 12.21 152 444361 20.00 ug/1 -0.03 10) Naphthalene-d8 15.84 136 1596546 20.00 ug/1 -0.04 17) Acenaphthene-diO 21.15 164 900797 20.00 ug/1 -0.03 30) Phenanthrene-diO 25.59 188 1317159 20.00 ug/1 -0.03 39) Chrysene-dl2 33.64 240 886900 20.00 ug/1 -0.04 45) Perylene-dl2 37.87 264 560997 20.00 ug/1 -0.04 System Monitoring Compounds 28) TCMX 23.29 209 39643 8.70 ug/L -0.04 Spiked Amount 10.000 Recovery = 87.00% 38) 2,4-DDD 0.00 235 0 0.00 ug/mL Spiked Amount 5.000 Recovery = 0.00% Target Compounds Qvalue 2) N-nitroso-dimethyl amine 5.85 74 99528 10.29 ug/1 95 3) bis(2-Chloroethyl)ether 11.61 93 241768 16.06 ug/1 99 4) 1,3-Dichlorobenzene 12.10 146 162708 10.48 ug/1 100 5) 1,4-Dichlorobenzene 12.25 146 175539 11.24 ug/1 99 6) 1,2-Dichlorobenzene 12.77 146 183210 12.63 ug/1 98 7) 2,2'-oxybis(1-Chioropropan 13.09 45 326757 15.71 ug/1 98 8) N-Nitroso-di-n-propylamine 13.47 70 156988 15.90 ug/1 99 9) Hexachloroethane 13.62 117 34657 6.06 ug/1 93 11) Nitrobenzene 13.88 77 215836 15.42 ug/1 97 12) Isophorone 14.54 82 358558 13.54 ug/1 99 13) bis(2-Chloroethoxy)methane 15.22 93 285789 16.57 ug/1 99 14) 1,2,4-Trichlorobenzene 15.73 180 163232 13.45 ug/1 98 15) Naphthalene 15.90 128 610321 15.90 ug/1 99 16) Hexachlorobutadiene 16.45 225 27994 4.61 ug/1 97 18) Hexachlorocyclopentadiene 18.63 237 4505 1.13 ug/1 # 97 19) 2-Chloronaphthalene 19.40 162 378695 15.94 ug/1 98 20) Dimethylphthalate 20.49 163 509131 18.59 ug/1 99 21) 2,6-Dinitrotoluene 20.71 165 102628 15.67 ug/1 99 22) Acenaphthylene 20.68 152 564011 16.97 ug/1 100 2 3) Acenaphthene 21.24 153 402242 17.02 ug/1 99 24) 2,4-Dinitrotoluene 21.87 165 134343 15.58 ug/1 98 25) Diethylphthalate 22.62 149 485678 18.49 ug/1 99 26) 4-Chlorophenyl-phenylether 22.78 204 210217 18.03 ug/1 98 27) Fluorene 22.75 166 451235 18.04 ug/1 98 29) Azobenzen/ 1,2-Diphenylhyd 23.24 77 421315 15.16 ug/L 98 31) N-Nitrosodiphenylamine • 23.17 168 136157 12.43 ug/1 98 32) 4-Bromophenyl-phenylether 24.25 248 116908 18.28 ug/1 92 (#) = qualifier out of range (m) = manual integration REFA1.D GCMS0412.M Fri Apr 26 09:30:36 2002 Page 1

NYC-WTC_000049414