GCMS analysis results for sample AE08936, April 29 2002

NYC 9/11 Public Portal Document Library Search Compound Report . Data File : C:\MSDCHEM\1\DATA\042202\8936.D Vial: 9 Acq On : 22 Apr 2002 5:43 pm Operator: Bohik Sample : SAMPLE 8936 4/15/02 Inst : Instrumen Mise Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\MSDCHEM\1\5973N\5080402BBC.M (RTE Integrator) Title : Quantitation For Method 508gcscan Library : C:\DATABASE\WILEY7N.L

Peak Number 2 2-Amino-4-hydroxypyrrolo[2,... Concentration Rank 2 R.T. EstConc Area Relative to ISTD R.T. 10.27 0.83 ug/L 49154 1,4-Dichlorobenzene-d4 9.41 Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 2-Amino-4-hydroxypyrrolo[2,3-d]p... 150 C6H6N4O 000000-00-0 9 2 2,3-Epoxypropyl 4-nitrobenzene $... 223 C10H9NO5 013318-11-1 9 3 lH-Pyrazole, 3-methyl-5-(trifluo... 150 C5H5F3N2 010010-93-2 7 4 Benzo[b]thiophene-4rol (CAS) $$ ... 150 C8H6OS 003610-02-4 7 Abundance Scan 1223 (10.265 mln): 8936.D (-) m/z 150.00 100.00% 150

5000 52 78 115

*w... 10.00 10.20 10.40 10.60 m/z 152.00 64.59% m/z-> Abundance 0- • 1 ■ ■ • • 1 • 20 40 I ' ‘ 60 ’II i66"i2O 140 160 180 "266 220 80 #45711:2-Amino-4-hydroxypyrrolo 2,3-d]pyrimidine A 110 43

5000 133 10.00 10.20 10.40 10.60 m/z 115.00 55.78% 80 108 L 64 II 121 | । 0- miz-> 20 40 60 80 100 120 140 160 160 260 220 Abundance #149106:2,3-Epoxypropyl 4-nitrobenzene $$ Oxiranemethanol... 150 LL 10.00 10.20 10.40 10.60 5000 m/z78.10 48.36%

104 56 76 J 92 120 134 167 223

Win 0- ■ ■ i • •' • 111 1 ■ ■ ■11 • • ‘I • ■ i • • •11 miz-> 20 40 60 80 100 120 140 160 180 200 220 ’ Abundance #45564: 1H-Pyrazole, 3-methyl-5-(trifluoromethyl)- $$ Pyra... 150 10.00 10.20 10.40 10.60 m/z 52.10 31.86%

5000 81 101 28 51 69 131

■n/z-> 0 15,41ll TT 120 140' 160 i66' 266'’226 20 40 60 80 100 ' 10.00 10.20 10.40 10.60

8936.D 5080402BBC.M Thu Apr 25 14:32:13 2002 Page 4

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