GCMS calibration results for DFTPP, April 15, 2002

NYC 9/11 Public Portal Document

Quantitation Report (QT Reviewed)

Data File C:\HPCHEM\1\DATA\APR12O2\CAL Vial: 2 Acq On 15 Apr 2002 9:04 am Operator: Sample 20 Inst : 209 Mise Multiplr: 1.00 MS Integration Params: GOOFY.P Quant Time: Apr 16 14:44 2002 Quant Results File: GCMS0412.RES

Quant Method : C:\HPCHEM\1\METHODS\GCMS0412.M (RTE Integrator) Title : 209 625/TCLP calibration table Last Update : Tue Apr 16 11:47:07 2002 Response via : Initial Calibration DataAcq Meth : GCMS0412

Internal Standards R.T. Qlon Response Cone Units Dev(Min)

1) 1,4-Dichlorobenzene-d4 12.23 152 554668 20.00 .ug/l 0.00 10) Naphthalene-d8 15.87 136 2064508 20.00 ug/l 0.00 17) Acenaphthene-diO 21.17 164 1194799 20.00 ug/l 0.00 30) Phenanthrene-diO 25.62 188 1826235 20.00 ug/l 0.00 39) Chrysene-dl2 33.68 240 1218819 20.00 ug/l 0.00 45) Perylene-dl2 37.91 2 64 780366 20.00 ug/l 0.00

System Monitoring Compounds 28) TCMX 0.00 209 0 0.00 ug/L Spiked Amount 10.000 Recovery = 0.00% 38) 2,4-DDD 0.00 235 0 0.00 ug/mL Spiked Amount 5.000 Recovery = 0.00%

Target Compounds /4-2h Qvalue 2) N-nitroso-dimethyl amine 5.87 74 230214 19.07 ug/l 98 3) bis(2-Chloroethyl)ether 11.64 93 376035 20.01 ug/l 98 4) 1,3-Dichlorobenzene 12.13 146 394024 20.34 ug/l 99 5) 1,4-Dichlorobenzene 12.28 146 399159 20.47 ug/l 100 6) 1,2-Dichlorobenzene 12.79 146 371579 20.52 ug/l 98 7) 2,2'-oxybis(l-Chloropropan 13.11 45 492045 18.95 ug/l 98 8) N-Nitroso-di-n-propylamine 13.51 70 240017 19.48 ug/l 98 9) Hexachloroethane 13.64 117 141848 19.86 ug/l 97 11) Nitrobenzene 13.92 77 356625 19.70 ug/l 98 12) 1sophorone 14.56 82 676830 19.76 ug/l 100 13) bis(2-Chloroethoxy)methane 15.24 93 443268 19.87 ug/l 99 14) 1,2,4-Trichlorobenzene 15.76 180 328060 20.90 ug/l 99 15) Naphthalene 15.92 128 1025691 20.66 ug/l 99 16) Hexachlorobutadiene 16.46 225 168684 21.49 ug/l 99 18) Hexachlorocyclopentadiene 18.66 237 98141 18.57 ug/l 97 19) 2-Chloronaphthalene 19.43 162 633706 20.11 ug/l 99 20) Dimethylphthalate 20.52 163 729736 20.09 ug/l 99 21) 2,6-Dinitrotoluene 20.73 165 171867 19.79 ug/l 100 22) Acenaphthylene 20.70 152 895876 20.32 ug/l 100 23) Acenaphthene 21.26 153 638072 20.36 ug/l 100 24) 2,4-Dinitrotoluene 21.90 165 221893 19.41 ug/l 95 25) Diethylphthalate 22.65 149 702392 20.16 ug/l 99 26) 4-Chlorophenyl-phenylether 22.81 204 340213 22.01 ug/l 98 27) Fluorene 22.78 166 713639 21.50 ug/l 97 2 9) Azobenzen/ 1,2-Diphenylhyd 23.28 77 696368 18.89 ug/L 96 31) N-Nitrosodiphenylamine 23.20 168 318111 20.94 ug/l 99 32) 4-Bromophenyl-phenylether 24.28 248 186095 20.99 ug/l 94 (#) = qualifier out of range (m) = manual integration CAL10.D GCMS0412.M Tue Apr 16 14:46:19 2002 Page 1

NYC-WTC_000048706