GCMS calibration verification data for volatile organics, Apr 2002

NYC 9/11 Public Portal Document

Quantitation Report (QT Reviewed)

Data File C:\HPCHEM\l\DATA\APR2402\C 50 . Vial: 2 Acq On 24 Apr 2002 4:49 pm Operator: Sample Inst : 209 Mise Multiplr: 1.00 MS Integration Params: GOOFY.P Quant Time: Apr 25 9:52 2002 Quant Results File: GCMS0412.RES

Quant Method : C:\HPCHEM\1\METHODS\GCMS0412.M (RTE Integrator) Title : 209 625/TCLP calibration table Last Update : Wed Apr 17 11:48:30 2002 Response via : Initial Calibration DataAcq Meth : GCMS0412

Internal Standards R.T. Qlon Response Cone Units Dev(Min)

1) 1,4-Dichlorobenzene-d4 12.21 152 429477 20.00 ug/1 -0.03 10) Naphthalene-d8 15.85 136 1552169 20.00 ug/1 -0.03 17) Acenaphthene-diO 21.15 164 885684 20.00 ug/1 -0.03 30) Phenanthrene-diO 25.59 188 1314326 20.00 ug/1 -0.03 39) Chrysene-dl2 33.65 240 859884 20.00 ug/1 -0.03 45) Perylene-dl2 37.87 264 517881 20.00 ug/1 -0.04

System Monitoring Compounds 2 8) TCMX 0.00 209 0 0.00 ug/L Spiked Amount 10.000 Recovery = 0.00% 38) 2,4-DDD 0.00 235 0 0.00 ug/mL Spiked Amount 5.000 Recovery = 0.00%

Target Compounds 2) N-nitroso-dimethyl amine 5.86 74 434285 35/(7 46.46 ug/1 Qvalue 98 3) bis(2-Chloroethyl)ether 11.63 93 674362 46.35 ug/1 98 4) 1,3-Dichlorobenzene 12.11 146 741773 49.44 ug/1 99 5) 1,4-Dichlorobenzene 12.26 146 751395 49.77 ug/1 100 6) 1,2-Dichlorobenzene 12.77 146 697678 49.76 ug/1 100 7) 2,2'-oxybis(1-Chloropropan 13.10 45 898109 44.68 ug/1 97 8) N-Nitroso-di-n-propylamine 13.49 70 436506 45.75 ug/1 99 9) Hexachloroethane 13.62 117 267858 48.42 ug/1 98 11) Nitrobenzene 13.90 77 655051 48.14 ug/1 99 12) Isophorone 14.55 82 1244406 48.33 ug/1 99 13) bis(2-Chloroethoxy)methane 15.23 93 813614 48.51 ug/1 99 14) 1,2,4-Trichlorobenzene 15.73 180 615591 52.17 ug/1 98 15) Naphthalene 15.91 128 1876612 50.29 ug/1 100 16) Hexachlorobutadiene 16.45 225 317989 53.89 ug/1 98 18) Hexachlorocyclopentadiene 18.64 237 226519 57.83 ug/1 99 19) 2-Chloronaphthalene 19.41 162 1176480 50.37 ug/1 98 20) Dimethylphthalate 20.50 163 1344984 49.95 ug/1 99 21) 2,6-Dinitrotoluene 20.72 165 319471 49.62 ug/1 98 22) Acenaphthylene 20.68 152 1629090 49.85 ug/1 100 23) Acenaphthene 21.25 153 1161891 50.02 ug/1 99 24) 2,4-Dinitrotoluene 21.88 165 412658 48.69 ug/1 96 25) Diethylphthalate 22.64 149 1261632 48.85 ug/1 99 26) 4-Chlorophenyl-phenylether 22.78 204 601206 52.46 ug/1 100 27) Fluorene 22.76 166 1255672 51.04 ug/1 99 29) Azobenzen/ 1,2-Diphenylhyd 23.25 77 1241190 45.41 ug/L 99 31) N-Nitrosodiphenylamine 23.19 168 554611 50.73 ug/1 98 32) 4-Bromophenyl-phenylether 24.25 248 335729 52.62 ug/1 96

(#) = qualifier out of range (m) = manual integration CAL50.D GCMS0412.M Thu Apr 25 09:56:00 2002 Page 1

NYC-WTC_000043341