GCMS analysis results sample AE08486, May 2002

NYC 9/11 Public Portal Document Library Search Compound Report Data File : C:\MSDCHEM\1\DATA\020419\08483.D Vial: 20 Acq On : 20 Apr 2002 2:50 am Operator: Nefliu Sample : sample Inst : Instrumen Mise Multiplr: 1.00 MS Integration Params: rteint.e Quant Method : C:\MSDCHEM\1\METHODS\SCAN020418.M (Chemstation Integrator) Title : Method 508 GC/MS Scan Library : C:\DATABASE\nist98.1 ********************************************************************* Peak Number 3 3,3-Dimethylbutylamine Concentration Rank 5 R.T. EstConc Area Relative to ISTD R.T. 6.34 0.26 ug/1 354282 1,4-Dichlorobenzene-d4 11.38 Hit# of 5 Tentative ID MW MolForm CAS# Qual 1 3,3-Dimethylbutylamine 101 C6H15N 015673-00-4 4 2 1,3-Dioxolan-2-one 88 C3H403 000096-49-1 3 3 1,3-Dioxolan-2-one 88 C3H403 000096-49-1 3 4 1,3-Dloxolan-2-one 88 C3H403 000096-49-1 3 Abundance Scan 555 (6.340 min): 08483.D (-554) (-) m/z 40.10 100.00% 40

5000

45 57 83 88 101 — 6.00 6.20 6.40 6.60 ■ ■ i ■ ■ ■ • i ■ ■ ■ ■ i ■ ■ ■ 1 I ' L51 ■ ■ i ■ • • ■ i ■ 1 ■ ■ i ■ • i > • • • i m/z 43.10 38.76% niz-> 10 20 30 40 50 60 70 80 90 100 110 Abundance #722:3,3-Dimethylbutylamine 30

50001 ■ ■ i 1 ■ ' ■ i ■ ■ • • i • ■ ■ • । 1 1 1 1 I 6.00 6.20 6.40 6.60 m/z 83.20 22.25% 18 41.46 51 57 69 i । । i l ri । । i ■ i i i । i । ‘ ■ i ‘ 1 ‘ ■ i ‘ 86 101 1 ■ i 1 • ■ ' i ■ ■ ■ ' i n/z-> 10 20 30 40 50 60 70 80 90 100 110 Abundance #108061:1,3-Dioxolan-2-one 29 TTTtr 6.00 6.20 6.40 6.60 5000 43 m/z 39.00 21.88% 88

58 PTH * 14411 1411 I 10 20 30 40 50 60 70 80 90 100 110 Abundance #108062:1,3-Dioxolan-2-one ■ • i' ‘ her ..7 , 29 6.00 6.20 6.40 6.60 43 m/z 88.00 19.79% 88 5000

58 TP— I............ I.............. 73........... ■ ■ । ■ ■ i ■ ■ 1 1 i ■ ■ ‘ ' I 1 1 1 1 1 1 1 122 /z—> 10 20 30 40 50 60 70 80 90 100 110 6.00 6.20 6.40 6.60

08483.D SCAN020418.M Thu May 02 11:44:58 2002 Page 5

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