GCMS calibration results for volatile organics, Apr-May 2002

NYC 9/11 Public Portal Document

Quantitation Report (QT Reviewed) Data File : C:\MSDCHEM\l\DATA\020419\0419C3.D Vial: 2 Acq On : 19 Apr 2002 8:50 am Operator: Nefliu Sample : ccv Inst : Instrumen Mise : Multiplr: 1.00 MS Integration Params: EVENTS.E Quant Time: Apr 19 13:34:29 2002 Quant Results File: SCAN020418.RE

Quant Method : C:\MSDCHEM\1\METHODS\SCAN020418.M (Chemstation Integrator) Title : Method 508 GC/MS Scan Last Update : Fri Apr 19 13:32:16 2002 Response via : Initial Calibration DataAcq Meth : 508SCAN1 Internal Standards R.T. Qlon Response Cone Units Dev(Min) 1) 1,4-Dichlorobenzene-d4 11.38 152 10057125 40.00 ug/1 -0.03 10) Naphthalene-d8 16.55 136 38315888 40.00 ug/1 -0.03 17) Acenaphthene-diO 24.47 164 20066166 40.00 ug/1 -0.03 3 0) Phenanthrene-dl0 31.73 188 29521921 40.00 ug/1 -0.03 38) Chrysene-dl2 39.95 240 21766967 40.00 ug/1 -0.02 44) Perylene-dl2 43.16 264 14380825 40.00 ug/1 -0.01 System Monitoring Compounds 27) TCMX 27.55 207 1191117 9.56 ug/1 -0.03 Spiked Amount 10.000 Recovery = 95.60%

Target Compounds A-5D7 • 35-(sQvalue n 2) N-nitrosodimethylamine 3.87 74 6941070 42.27 ug/1 96 3) bis(2-Chloroethyl)ether 10.66 93 15830366 47.62 ug/1 98 4) 1.3-Dichlorbenzene 11.12 146 17776856 49.99 ug/1 98 5) 1,4-Dichlorobenzene 11.44 146 19469061 50.45 ug/1 99 6) 1,2-Dichlorobenzene 11.96 146 16909796 49.93 ug/1 97 7) 2,2'oxybis(1-Chloropropane 12.79 45 22705733m 48.50 ug/1 8) N-Nitroso-di-n-propylamine 13.28 43 8136608 46.68 ug/1 99 9) Hexachloroethane 13.26 119 6411375 48.50 ug/1 98 11) Nitrobenzene 13.69 77 12690208 45.08 ug/1 98 12) 1sophorone 14.80 82 26210236 47.29 ug/1 96 13) bis(2-Chloroethoxy) methan 16.04 93 18707849 47.89 ug/1 98 14) 1,2,4-Trichlorobenzene 16.39 180 13918825 51.12 ug/1 97 15) Naphthalene 16.63 128 45608447 49.91 ug/1 99 16) Hexachlorobutadiene 17.40 225 6172813 50.27 ug/1 98 18) 2-Chloronaphthalene 21.94 162 25594388 52.22 ug/1 96 19) Acenaphthylene 23.77 152 45945364 51.24 ug/1 100 20) Dimethyl phthalate 23.88 163 29850318 49.72 ug/1 100 21) 2,6-Dinitrotoluene 23.99 77 1111142 37.95 ug/1 # 89 2 2) Acenaphthene 24.62 153 25434545 50.12 ug/1 98 23) 2,4-Dinitrotoluene 25.76 165 4653191 39.94 ug/1 91 24) Fluorene 27.03 166 29955471 51.06 ug/1 100 25) Diethyl phthalate 27.25 149 26103839 48.69 ug/1 98 26) 4-Chlorophenyl-phenylether 27.36 204 13421951 50.85 ug/1 96 28) N-Nitrosodiphenylamine 27.96 168 8707767 46.36 ug/1 99 29) Azobenzene 28.04 77 30326515 48.48 ug/1 97 31) Hexachlorobenzene 29.62 284 8035671 53.27 ug/1 97 32) 4-Bromophenyl-phenylether 29.73 248 7393009 51.59 ug/1 95 3 3) Phenanthrene 31.83 178 42365941 51.42 ug/1 98 3 4) Anthracene 32.07 178 43053841 50.79 ug/1 100 35) Di-n-butylphthalate 34.82 149 50533124 48.82 ug/1 99 (#) = qualifier out of range (m) = manual integration 0419C3.D SCAN020418.M Fri May 03 10:45:10 2002 Page 1

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