GCMS surrogate recovery results, April 22 2002

NYC 9/11 Public Portal Document

Library Search Compound Report

Data File : C:\MSDCHEM\l\DATA\020417\08260.D Vial: 17 Acq On : 17 Apr 2002 10:40 pm Operator: Nefliu Sample : sample Inst Instrumen Mise Multiplr: 1.00 MS Integration Params: LSCINT.e

Quant Method : C:\MSDCHEM\1\METHODS\041702SCAN.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Library : C:\DATABASE\NIST98.L ********************************************************************* Peak Number 3 4-Penten-2-one Concentration Rank 8

R.T. EstConc Area Relative to ISTD R.T.

3.78 0.22 ug/L 244262 1,4-Dichlorobenzene-d4 9.99

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 4-Penten-2-one 84 C5H80 013891-87-7 4 2 2-Propanone, 1-fluoro- 76 C3H5FO 000430-51-3 4 3 Hydrogen azide 43 HN3 007782-79-8 3 4 3-Oxobutyric acid, 2-chloroethyl... 164 C6H9C103 1000210-13-3 2 Abundance Scan 119 (3.778 min) 08260.D (-116) (-) m/ z 43.10 100.00% 43

5000

FMPTP 35 .49 63 7 6 83 91 3.40 3 60 3 80 4.00 4 20 0+ mpmmm ........... >.......I.LinIo... . m/ z 40.00 28.52% •n/z—> Abundance 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 #4029: 4-Penten-2-one 43

5000 3.40 3.60 3 80 4.00 4.20 39 m/z 82.90 12.34% 15 27 84

n/z-> -H+ 0+ ■■ i" ■ ■ r■1 TIT +m. 50 55 69 I m 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 i ■ " ' i1

Abundance #3864: 2-Propanone, 1-fluoro- 43 as_,1_A rr -_ —+A 340 3 60 3.80 4.00 4.20 5000- 15 m/z 35.10 10.94%

33 27 38 । 47 61 76

Tl/Z-> 0+ -7+ ml+ HI । It 11| l mmmm 5" 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 Abundance #3862: Hydrogen azide 43 3.40 3 60 3.80 4 00 4.20 m/z 63.10 10.59%

5000 15 28

0 n/z--> 3 10 15 20 25 30 35 40 45' r ' "50i" ''55i1" 6011' " 651 r 1"7011'175' i " 1 80■ i ■ " 85' r ■ "90r' "95i ' i"1 > i" ■■ i" 3.40 3.60 3 80 4 00 4 20

08260.D 041702SCAN.M Thu Apr 18 09:45:50 2002 Page 8

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