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GCMS analysis results for sample AE08252, April 2002

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Laboratory report documenting GCMS analysis of sample AE08252 conducted on April 19, 2002, including surrogate recovery data.

NYC-WTC_000047802–000047829

Folder label: “GCMS X 4/8/02 A 4/17/02

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NYC 9/11 Public Portal Document

Library Search Compound Report

Data File : C:\MSDCHEM\1\DATA\020417\08252.D Vial: 10 Acq On : 17 Apr 2002 4:52 pm Operator: Nefliu Sample : sample Inst Instrumen Mise Multiplr: 1.00 MS Integration Params: LSCINT.e

Quant Method : C:\MSDCHEM\1\METHODS\041702SCAN.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Library : C:\DATABASE\NIST98.L

Peak Number 6 Butenol, methyl- Concentration Rank 2

R.T. EstConc Area Relative to ISTD R.T.

4.98 0.43 ug/L 451930 1,4-Dichlorobenzene-d4 9.99

Hit# Of 5 Tentative ID MW MolForm CAS# Qual

1 Butenol, methyl- 86 C5H10O 060766-00-9 64 2 3-Buten-2-ol, 2-methyl- 86 C5H10O 000115-18-4 50 3 3-Buten-2-ol, 2-methyl- 86 C5H10O 000115-18-4 38 4 3-Buten-2-ol, 2-methyl -____________ 86 C5H10O 000115-18-4 38 Abundance Scan 324 (4 983 min): 08252.0 (-318) (-) m/z 71.10 100.00% 43 71

5000 59 55 -------- 39 49 4 60 4.80 5 00 5 20 5.40

n/z--> 5 ol ' r " ■ i ■ ■" i1" ■ i ■ " ' i " 10 15 20 25 ——4— 30 67 | | 8588 -' I ”111"'111" H "1' i" " r ' 35 40 45 50 55 60 65 70 75 80 85 90 95 m/z 43.10 91.56% Abundance #24435: Butenol, methyk 43 71

5000 27 59 ANU uAap TP/ [ 4 60 4 80 IMAMWs 5 00 5 20 5 40 15 31 39 m/z 41.05 67.74% 53 2 18i"l ■■ 24 । ■ 1111II 6.5456/ HH ' I' i1 " 11" " 111111" " 111 63 67 157— .74 79 83 86 ol 1111 r.. 36 n/z—> 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 Abundance #114555 3-Buten-2-ol. 2-methyl- 71 43 MN MMMM 4.60 4.80 500 5.20 5 40 5000 m/z 69.10 43.01% 59 27 31 39 53 1518 86 ol HLl TTH +,—50HH+ 1 561 mH I <11 ■ 1111 ■ 111111 n/z-> 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 Abundance #24438: 3-Buten-2-ol, 2-methyl- A M 71 4.60 4.80 5 00 5 20 540 m/ z 59.10 39.78% 43 5000 59 27 31 39 1518 50 53। 56 । 62 - 6/ , — 0 I ' I1 1 I 1 | "" | I 1 । '| " I I | । Il 1—Pr ill I1 + IHHHt . I " " 11183"18611111" " 111 Tl/Z--> 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 4 60 4.80 5.00 5.20 5.40

08252.D 041702SCAN.M Thu Apr 18 09:13:57 2002 Page 11

NYC-WTC_000047816

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NYC-WTC_000047816Source: NYC Law Department, mirrored locally

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