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GCMS analysis results, sample AE07513, April 2002

Machine-extracted title · confidence 100%

Laboratory report documenting GCMS analysis of environmental sample AE07513 conducted on April 11, 2002.

NYC-WTC_000047355–000047366

Folder label: “GCMS X 4/2/02 A 4/4/02

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NYC 9/11 Public Portal Document

Library Search Compound Report

Data File C:\MSDCHEM\l\DATA\020404\07513.D Vial: 9 Acq On 4 Apr 2002 2:26 pm Operator: Nefliu Sample sample Inst : Instrumen Mise Multiplr: 1.00 MS Integration Params: LSCINT.e

Quant Method : C:\MSDCHEM\1\METHODS\SCAN020403.M (Chemstation Integrator) Title : Method 508 GC/MS Scan Library : C:\DATABASE\nist98.1 Peak Number 3 2-Butyne-1,4-diol Concentration Rank 3 R.T. EstConc Area Relative to ISTD R.T. 3.33 0.13 ug/1 83968 1,4-Dichlorobenzene-d4 10.66 Hit# of 5 Tentative ID MW MolForm CAS# Qual

l 2-Butyne-l,4-diol 86 C4H6O2 000110-65-6 3 2 Imidazol, 4-fluoro- 86 C3H3FN2 030086-17-0 2 3 Ethyl Chloride 64 C2H5C1 000075-00-3 2 4 Acetic acid, chloro-, ethyl ester 122 C4H7C102 000105-39-5 1 Abundance Scan 42 (3.326 min): 07513.D (-41) (-) m/z 49.10 100.00%

5000 40 49

86 A"Munt ′′ I ' ■ ' ■ l ' - ■ ■ I I" " I " '' I " " I' 3.20 3.30 3.40 3.50 3.60 3.70 0 " i " " i " 111" " i " " r ■ " i" " i " " r ' i1' ‘11" " r " ■ r "' r " 11" " r " 11 " i " " r m/z 40.10 82.04% n/z-> 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 Abundance #108388: 2-Butyne-1,4-diol 29 39 57

5000 " ' i " 1' i " " i " ' • i 1111" ' 111 " 11 68 3.20 3.30 3.40 3.50 3.60 3.70 26 51 m/z 86.00 54.58% 43

n/z-> Of " I"'' I " ‘11" —3334 1471lf 460..65+ 11111 717477 81111185 u' ।11 11'! ।! ।' 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 Abundance #34862: Imidazol, 4-fluoro- 85

3.20 3 30 3.40 3.50 3.60 3.70 5000 m/ z 47.00 15.85%

59

Ot T1UTTTU‘TTTETCTTTTTTUTTTTTTTTTTTTTITTTTTTTTTTTTTHTTT '' I * * " I'11' 111'11'''11 HTp A MA

Tl/Z-> 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 Abundance #107943: Ethyl Chloride 1 r i11 ■ ■ । ■ 23 3.20 3.30 3.40 3.50 3.60 3.70 m/z 51.00 1.06% 5000

49 64 rupoMP"Mo 25 35 1215 5 —1044 —8----H-604 60 ....... n/z-> 0 31 TT 111 ‘' I' ‘ " 111' T" " | " t111111 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 " I " ‘' I " " I ‘1'11 3.20 3.30 3.40 3.50 3.60 3.70 11111111111 p |

NYC-WTC_000047363

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