GCMS analysis report, sample AE07520, April 2002

NYC 9/11 Public Portal Document

Library Search Compound Report

Data File C:\MSDCHEM\l\DATA\020403\0402LB.D Vial: 10 Acq On 3 Apr 2002 5:21 pm Operator: Nefliu Sample 04/02 lab blk Inst Instrumen Mise Multiplr: 1.00 MS Integration Params: LSCINT.e

Quant Method : C:\MSDCHEM\1\METHODS\SCAN020403.M (Chemstation Integrator) Title : Method 508 GC/MS Scan Library : C:\DATABASE\nist98.1 Peak Number 1 2-Butyne-1,4-diol Concentration Rank 8

R.T. EstConc Area Relative to ISTD R.T. 3.28 0.23 ug/1 154070 1,4-Dichlorobenzene-d4 10.66

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 2-Butyne-1,4-diol 86 C4H602 000110-65-6 3 2 Imidazol, 4-fluoro- 86 C3H3FN2 030086-17-0 2 3 Krypton 84 Kr 007439-90-9 2 4 Ethyl Chloride 64 C2H5C1 000075-00-3 1 Abundance Scan 34 (3.279 min): 0402LB.D (-22) (-) m/z 84.00 100.00%

5000 49 84

M 40 "1111‘‘110200011-10TTTT—-TIIIT 3.20 3.30 3.40 3.50 3.60 3.70 0 111,1 ■ r ' ■1 r '1' i' '1 • i' ■' ■ i' ■ 1 ' i'' ■ ■ । '111 m/ z 49.10 78.96% m/z-> 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 Abundance #108388: 2-Butyne-1,4-diol 29 39 57

5000 1111 *1' ■ ।111 ■ । ■11111 ■ ■ ■ rri 111111 68 3.20 3.30 3.40 3 50 3.60 3.70 26 43 51 m/z 86.00 51.37%

m/z- > Oh TII" 15 20 Abundance ,14 3336 25 30 35 40 lbs +5 160,-65+ , 71 74 77 45 50 55 60 65 70 #34862: Imidazol, 4-fluoro- 81! 85 1 H | I I । i | । | | । । r T| l ri i । । । । i । i i 75 80 85 90 95 A/MMaMokun,,, 85

3.20 3.30 3.40 3.50 3.60 3.70 5000 m/ Z 47.00 50.37%

/ AWWWA WM II 59

Oh —ITIWWTTIWTWITTTTIPITTT >11 > • ■ • । I ■ i ■ • ■ ■ i ■ • ■ ■ i i ■ ■ i > ■ >11 ■

m/z-> 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 Abundance #33829: Krypton ■ ■ i ■ • - ■ i111 > ।1 ■ ।r i > 11111 84 3.20 3.30 3.40 3.50 3.60 3.70 m/z 51.00 31.86% 5000

42 ww/"eyaninas 80 Oh —1 ■ ■ i ■ ■ ■ ■ । ■ 111 ‘ 1 1 ' I ' ■ '1 i ■ ■ ■' 1 1 ' 11 I' 1 11 11 1 m/z-> 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 3.20 3.30 3.40 3.50 3 60 3.70

0402LB.D SCAN020403.M Thu Apr 04 10:14:17 2002 Page 3

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