GCMS analysis results, sample AE07513, April 2002

NYC 9/11 Public Portal Document

Library Search Compound Report

Data File C:\MSDCHEM\1\DATA\020404\07513.D Vial: 9 Acq On 4 Apr 2002 2:26 pm Operator: Nefliu Sample sample Inst : Instrumen Mise Multiplr: 1.00 MS Integration Params: LSCINT.e Quant Method : C:\MSDCHEM\1\METHODS\SCAN020403.M (Chemstation Integrator) Title : Method 508 GC/MS Scan Library : C:\DATABASE\nist98.1

Peak Number 1 2-Butyne-1,4-diol Concentration Rank 2

R.T. EstConc Area Relative to ISTD R.T. 3.27 0.15 ug/1 96228 1,4-Dichlorobenzene-d4 10.66

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 2-Butyne-l,4-diol 86 C4H602 000110-65-6 3 2 Imidazol, 4-fluoro- 86 C3H3FN2 030086-17-0 2 3 2-Methyl-3-vinyl-oxirane 84 C5H80 006790-37-0 1 4 2-Chloroethanol 80 C2H5C1O 000107-07-3 1 Abundance Scan 33 (3.273 min): 07513. D (-26) (-) m/ z 47.10 100.00% 47 84 M 40 51 5000

1' 1" 1' I'1 3 20 3.30 3.40 3.50 3.60 3.70 Oh ■ I >1 ■ ■ । । ‘ 1 ■ ■ 1111' i ■ m/z 49.10 95.56% m/z-> 15 Abundance 20 25 30

29 35 40

39 45 50 55 #108388: 2-Butyne-1,4-diol 57 60 65 70 75 80 85 90 95 AMuowt 5000 68 3.20 3.30 3 40 3.50 3.60 3.70 26 51 m/z 84.00 63.33% 43

miz-> Oh TII" 15 20 1113336/ 25 +471 11 1Irusuyll 60 65 +717477.81. Tmpmi 30 35 40 45 50 55 60 65 70 75 80 85 90 95 v/Moywantu Abundance #34862: Imidazol, 4-fluoro- 85 i ■ ■ ■ ■ i'' ■ ■ i i1' • ■ i ■ ■ ■ ■ i ■'

3.20 3.30 3.40 3.50 3.60 3.70 5000 m/z 86.00 54.63%

59 w.MLp-wrwitn Oh —IIIPTTTITIT " i'' ■ ■ i ■ 111 " 11111111 PTTITT n/z-> 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 Abundance #1297: 2-Methyl-3-vinyl-oxirane 39 55 3.20 3.30 3.40 3.50 3.60 3.70 m/z 40.10 XA~RA~-~- 49.44% 45 5000 83 27 69

/z-> Oh III" 15 20 .11131...361 + Tt+T 25 30 48 51 3550 42 ++ 58 63 66 40 45 55 It I | I I ! I | I I I

60 65 77 ,86 | t I I ' I'' >' 111111111

70 75 80 85 ■ r ■'11' 90 95 3.20 3.30 3.40 3.50 3.60 3.70

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