GCMS reference standard results for volatile organics, May 2002

NYC 9/11 Public Portal Document

Quantitation Report (QT Reviewed)

Data File C:\HPCHEM\l\DATA\MAY0802\REFAl.D Vial: 14 Acq On 8 May 2002 11:17 pm Operator: Sample GC/MS SCAN 5/7 Inst : 209 Mise Multiplr: 1.00 MS Integration Params: GOOFY.P Quant Time: May 9 15:42 2002 Quant Results File: GCMS0507.RES

Quant Method : C:\HPCHEM\1\METHODS\GCMS0507.M (RTE Integrator) Title : 209 625/TCLP calibration table Last Update : Thu May 09 14:27:53 2002 Response via : Initial Calibration DataAcq Meth : GCMS0507

Internal Standards R.T. Qlon Response Cone Units Dev(Min)

1) 1,4-Dichlorobenzene-d4 12.19 152 454621 40.00 ug/1 0.00 10) Naphthalene-d8 15.83 136 1672961 40.00 ug/1 0.00 17) Acenaphthene-diO 21.14 164 902964 40.00 ug/1 0.00 30) Phenanthrene-dlO 25.57 188 1232293 40.00 ug/1 0.00 38) Chrysene-dl2 33.64 240 640990 40.00 ug/1 0.00 44) Perylene-dl2 37.86 264 358056 40.00 ug/1 0.00

System Monitoring Compounds 2 8) TCMX 23.27 209 38487 8.57 ug/L 0.00 Spiked Amount 10.000 Recovery = 85.70%

Target Compounds Qvalue 2) N-nitroso-dimethyl amine 5.82 74 135536 11.84 ug/1 98 3) bis(2-Chloroethyl)ether 11.59 93 254652 17.15 ug/1 97 4) 1,3-Dichlorobenzene 12.09 146 171542 12.18 ug/1 96 5) 1,4-Dichlorobenzene 12.23 146 184228 11.95 ug/1 99 6) 1,2-Dichlorobenzene 12.75 146 187018 13.94 ug/1 99 7) 2,21-oxybis(1-Chloropropan 13.07 45 521400 18.11 ug/1 98 8) N-Nitroso-di-n-propylamine 13.46 70 193060 18.20 ug/1 97 9) Hexachloroethane 13.60 117 40570 7.40 ug/1 97 11) Nitrobenzene 13.87 77 227593 16.76 ug/1 99 12) Isophorone 14.52 82 536499 20.15 ug/1 97 13) bis(2-Chloroethoxy)methane 15.20 93 306650 17.78 ug/1 100 14) 1,2,4-Trichlorobenzene 15.71 180 157887 13.59 ug/1 98 15) Naphthalene 15.89 128 598726 17.39 ug/1 99 16) Hexachlorobutadiene 16.43 225 33955 6.32 ug/1 98 18) Hexachlorocyclopentadiene 18.63 237 12020 2.63 ug/1 98 19) 2-Chloronaphthalene 19.39 162 360776 18.29 ug/1 99 20) Dimethylphthalate 20.48 163 465578 18.74 ug/1 99 21) 2,6-Dinitrotoluene 20.70 165 87627 16.49 ug/1 93 22) Acenaphthylene 20.66 152 579457 16.48 ug/1 100 23) Acenaphthene 21.23 153 384386 18.34 ug/1 99 24) 2,4-Dinitrotoluene 21.86 165 98393 17.18 ug/1 96 25) Diethylphthalate 22.61 149 450038 20.23 ug/1 99 26) 4-Chlorophenyl-phenylether 22.77 204 189127 17.20 ug/1 99 27) Fluorene 22.74 166 419086 18.97 ug/1 98 29) Azobenzen/ 1,2-Diphenylhyd 23.24 77 471160 17.11 ug/L 97 31) N-Nitrosodiphenylamine 23.15 168 153687 19.97 ug/1 94 32) 4-Bromophenyl-phenylether 24.23 248 104172 17.09 ug/1 97 33) Hexachlorobenzene 24.67 284 121778 17.49 ug/1 95 34) Phenanthrene 25.64 178 550028 18.60 ug/1 99

(#) = qualifier out of range (m) = manual integration REFA1.D GCMS0507.M Thu May 09 15:43:27 2002 Page 1

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