GCMS calibration table for sample AE09447, May 2002

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Data File C: \HPCHEM\1\DATA\MAY0202\9447.D Vial: 6 Acq On 2 May 2002 7:41 pm Operator: Sample GC/MS SCAN 4/19 Inst : 209 Mise : Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\HPCHEM\1\METHODS\GCMS0501.M (RTE Integrator) Title : 209 625/TCLP calibration table Library : C:\DATABASE\NBS75K.L ********************************************************************* Peak Number 2 2-Pentanone, 4-hydroxy-4-methy Concentration Rank 1

R.T. EstConc Area Relative to ISTD R.T.

8.17 10.06 ug/1 841937 1,4-Dichlorobenzene-d4 12.20

Hit# Of 5 Tentative ID MW MolForm CAS# Qual

1 2-Pentanone, 4-hydroxy-4-methyl- 116 C6H12O2 000123-42-2 64 2 N,N1-Bis (2 -methyl-2-nitrosopentan-4 258 C12H22N2O4 094514-30-4 9 3 CH2=CHCH2C (O)OCH3 100 C5H802 003724-55-8 9 4 Acetone 58 C3H60 000067-64-1 7 Abundance Scan 341 (8.169 min): 9447. D (-) m/ z 43.05 100.00% 43

5000 59 . . । . . , , t , -r-. । . -i-. । . ‘i‘ 101 7.80 8.00 8.20 8.40 8.60 0 1 1 i 1 ' ’ 1 । 1 37, 1 ' I ' 1 1 1 I 1 Pi ' * 53, 69 83, ,. L, . _ — m/z 59.10 42.18% m/z—> 10 20 30 40 50 60 70 80 90 100 110 120 130 Abundance #64274: 2-Pentanone, 4-hydroxy-4-methyl- 43

5000 59 780 8.00 8.20 8.40 8.60 m/z 58.10 16.49% 27 I no 101 ( I 49 „ . .................................. 1.......................... TH ... . m/z-> 10 20 30 40 50 60 70 80 90 100 110 120 130 Abundance #35454: N,N'-Bis(2-methyl-2-nitrosopentan-4-one) 43 1 I o I I I I I _ I I I 1 I LI r I I I I I 1 7.80 8.00 8.20 8.40 8.60 5000 m/z 101.15 13.47%

99 115 27 I i j I i I ] l Tt| i i I i | i I I I [ I 56 I I ' I I I I I 72 I I 83 I I " I I ~ I I—u—i -l ' I _ I “ I | I I 1j l i 130 t I I I I I I I I I I I I I I

m/z-> 10 20 30 40 50 60 70 80 90 100 110 120 130 Abundance #1448: CH2=CHCH2C(O)OCH3 1 — — — — 1 11 I ni I 'l I I I I I I I

43 7.80 8.00 8.20 8.40 8.60 m/ z 41.15 7.04%

5000

58 37, „ 72........ 1Q0............ 1 i 1 ■ ■ ■ i 1 1 1 ' i 1 1 1 1 1 1 ' ■ ■ i ■ ■ ■■> i ■ I I I I Tnyd, I I I I I T I I I II TTR

m/z-> 10 20 30 40 50 60 70 80 90 100 110 120 130 7.80 8.00 8.20 8.40 8.60

9447.D GCMS0501.M Fri May 03 08:40:53 2002 Page 2

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