GCMS calibration table for sample AE09391, May 2002

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Library Search Compound Report

Data File C:\HPCHEM\1\DATA\MAY0102\9391.D Vial: 10 Acq On 1 May 2002 4:20 pm Operator: Sample gc/ms scan 4/18 Inst : 209 Mise Multiplr: 1.00 MS Integration Params: LSCINT.P

Quant Method C:\HPCHEM\1\METHODS\GCMS0501.M (RTE Integrator) Title 209 625/TCLP calibration table Library C:\DATABASE\NBS75K.L ********************************************************************* Peak Number 1 2-Pentanone, 4-hydroxy-4-methy Concentration Rank 1

R.T. EstConc Area Relative to ISTD R.T.

8.18 11.58 ug/1 760129 1,4-Dichlorobenzene-d4 12.21

Hit# Of 5 Tentative ID MW MolForm CAS# Qual A-------- 1 2-Pentanone/ 4-hydroxy-4-methyl- 116 C6H1202 000123-42-2 64 2 3-Hydroxy-2/pentanone 102 C5H10O2 003142-66-3 9 3 CH2=CHCH2C(O) OCH3 100 C5H802 003724-55-8 9 4 Morpholine/, 4-methyl- 101 C5H11NO 000109-02-4 5 Abundance Scan 343 (8.180 min): 9391 .D (-) m/z 43.05 100.00% 43

5000 59 । । । । 1 I I I I I I I I I I I I i I I I I l l 101 7.80 8.00 8.20 8.40 8.60 69 83 . | 1 1 i 1 'i 1 1 1 ' I 38— 53 , 11—i—i' -r-T * f (i I-“I I'll 1 1 ' I t I I 1 t I I I I I I I I I m/z 59.05 43.45% m/z-> 10 20 30 40 50 60 70 80 90 100 110 Abundance #64274: 2-Pentanone, 4-hydroxy-4-methyl- 4)3

5000 rj-r-r 1 1 [ Tl I I I I I I I 'l I I I I I I I

59 7.80 8.00 8.20 8.40 8.60 m/ z 58.10 15.54% 27 101 1 ' i ■ ' 1 ' i 1.49, .l, ' I ■ 1 ■ ■ i ■ 83 1 1 ■ i - m/z-> 10 20 30 40 50 60 70 80 90 100 110 Abundance #1691:3-Hydroxy-2-pentanone 31 59 I I 1 I ! l I t I I I I I I 1 I I I I I I I

780 8.00 8.20 8.40 8.60 5000 m/z 101.15 13.10% 45 15 , 66 73 84 102 1 1 I I III df 1 ' [ 1 l I I I 1 ' I 1 1 I'} I > ' I I ' ' I I I I ' ' I II-mI- I I > I I m/z-> 10 20 30 40 50 60 70 80 90 100 110 Abundance #1448: CH2=CHCH2C(O)OCH3 yr T I [ I I 11 l I i i i i t ! [ > I 43 7.80 8.00 8.20 8.40 8.60 m/ z 41.05 7.11%

5000

58 .................... 38 I I 72 100 1 i 1 1 1 ' i ' 1 1 ■ i ‘ 1 1 ■ i 1 1 ' 1 i 1 1 m/z-> 10 20 30 40 50 60 70 80 90 100 110 7.80 8.00 8.20 8.40 8.60

9391.D GCMS0501.M Wed May 08 14:14:32 2002 Page 1

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