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GCMS analysis results for sample AE10308, May 2002

Machine-extracted title · confidence 95%

Laboratory report documenting gas chromatography-mass spectrometry analysis of environmental sample AE10308 conducted on May 17, 2002.

NYC-WTC_000045171–000045188

Folder label: “GCMS X 5/1/02 A 5/8/02

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NYC 9/11 Public Portal Document Library Search Compound Report

Data File C:\MSDCHEM\1\DATA\050802\10308.D Vial: 11 Acq On 8 May 2002 9:56 pm Operator: Mclean Sample 5/1 eh Inst : Instrumen Mise Multiplr: 1.00 MS Integration Params: LSCINT.e Quant Method : C:\MSDCHEM\l\METHGDS\050102.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Library : C:\DATABASE\NIST98.L

Peak Number 9 3,7-Dimethoxyphenothiazine Concentration Rank 5

R.T. EstConc Area Relative to ISTD R.T.

34.99 0.55 ug/L 361002 Perylene-dl2 34.70 Hit# of 5 Tentative ID MW MolForm CAS# Qual 1 3,7-Dimethoxyphenothiazine 259 C14H13NO2S1 1000223-22-3 9 2 Glucosamine, 2,3,4,5-tetraacetyl- 347 C14H21NO9 1000127-35-95 3 7,12a-Dimethyl-l,2,3,4,4a,ll,12,. 264 C20H24 075758-27-9 5 4 5H-Naphtho[1,8-bc]thiophen-5-one... 264 C17H120S 010245-6575 5 Abundance Scan 5431 (34.990 min): 10308.D (-5429) (-) m/z 131.50 100.00% 131 259 fl

84 5000 115 281

208 34.60 34.80 35.00 35.20 35.40 O' '. . 44 | । . . I | ■ । I ! | — m/z 259.20 90.38% '' ।'111111 ■ ■ ।11'11"111 m/z-> 40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 340 Abundance #94475: 3,7-Dimethoxyphenothiazine 244209

5000 / _........................ ' i 1 1 1 1 i 17 1 ' I ' 1 1 ' i 1 1 ' ' i 1 1 130 34.60 34.80 35.00 35.20 35.40 173 216 201 m/z 264.10 63.78% 63 87 108 — 45 O-4 1.4444—1 r •r‘l i I 146 ’mn r i r "p111'1111— 1 I’’’ 11 I ' ' 1 ' I " 'U m/z->______ 40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 340 Abundance #8769: Glucosamine, 2,3,4,5-tetraacetyl- 43 - 34.60 34.80 35.00 35.20 35.40 5000 139 m/z 132.90 60.58% 97 259 115 69

m/z-> OU113 prmrkhephho Jil . 40 +4 15411 186211 229 T11 ■ 'I ■i11 " !''1 T’ 111 r" 60 80 100 120 140 160 180 200 220 240 260 280 300 320 340 288 312 330 347

Abundance #95110:7,12a-Dimethyl-1,2,3,4,4a,11,12,12a-octahydrochrysene 1 1 ' 1 1 1 1 1 264 34.60 34.80 35.00 35.20 35.40 m/z 84.00 57.05% 5000 /I 207 / 168 191 153 249 222 Otmmmmmmp li .1, Il', _ I I ■ ■ । ■ ■ ■ ■ । ।'1111111111' I '' i'1 ■■ i'1 ■11 TT" 1 Tl/Z-> 40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 340 34.60 34.80 35.00 35.20 35.40

10308.D 050102.M Thu May 09 13:52:32 2002 Page 12

NYC-WTC_000045187

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NYC-WTC_000045187Source: NYC Law Department, mirrored locally

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