GCMS reference data for sample AE10303, May 2002

NYC 9/11 Public Portal Document

Quantitation Report (QT Reviewed)

Data File C:\MSDCHEM\1\DATA\050802\501REFB.D Vial: 5 Acq On 8 May 2002 5:04 pm Operator: Mclean Sample 5/1 eh Inst : Instrumen Mise Multiplr: 1.00 MS Integration Params: EVENTS.E Quant Time: May 09 13:48:15 2002 Quant Results File: 050102.RES

Quant Method : C:\MSDCHEM\1\METHODS\050102.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Last Update : Tue May 07 09:57:23 2002 Response via : Initial Calibration DataAcq Meth : 508SCAN

Internal Standards R.T. Qlon Response Cone Units Dev(Min)

1) 1,4-Dichlorobenzene-d4 9.93 152 5017961 40.00 ug/L 0.00 10) Napthalene-d8 13.43 136 20007622 40.00 ug/L 0.00 17) Acenapthalene-dlO 18.57 164 10701062 40.00 ug/L 0.00 29) Phenanthranene-dlO 22.95 188 15681080 40.00 ug/L 0.00 37) Chrysene-dl2 30.81 240 12201261 40.00 ug/L 0.00 43) Perylene-dl2 34.70 264 8019542 40.00 ug/L 0.00

System Monitoring Compounds 27) TCMX 20.54 209 574384 7.18 ug/L 0.00 Spiked Amount 10.000 Recovery = 71.80% 50) 2,4-ddd 0.00 235 0 0.00 ug/L Spiked Amount 5.000 Recovery = 0.00%

Target Compounds Qvalue 2) n-nitros-dimethyl amine 3.89 74 709632 6.90 ug/L # 84 3) bis(2-Chloroethyl)ether 9.35 93 2776063 14.14 ug/L 88 4) 1,3-Dichlorobenzene 9.76 146 2397194 11.99 ug/L 97 5) 1,4-Dichlorobenzene 9.98 146 2483003 12.08 ug/L 100 6) 1,2-Dichlorobenzene 10.35 146 2451036 13.41 ug/1 100 7) 2,2‘oxybis(1-Chloropropane 10.81 45 4429859m 14.64 ug/L 8) N-nitroso-di-propylamine 11.13 70 2004228 14.40 ug/L 95 9) Hexachloroethane 11.26 117 712327 9.40 ug/L 89 11) Nitrobenzene 11.49 77 2673447 13.81 ug/L 92 12) Isophorone 12.20 82 5907779 16.94 ug/L 99 13) bis(2-Chloroethoxy) methan 12.94 93 3466487 15.01 ug/L 98 14) 1,2,4-Trichlorobenzene 13.30 180 2002162 13.66 ug/L 98 15) Napthalene 13.49 128 8459623 15.78 ug/L 97 16) Hexachlorobutadiene 13.93 225 801828 11.68 ug/L 99 18) 2-Chloronaphthalene 16.93 162 4720221 17.30 ug/L 98 19) Dimethylphthalate 18.00 163 5467107 15.63 ug/L 100 20) 2,6-Dinitrotoluene 18.11 165 812296 14.77 ug/L # 92 21) Acenapthylene 18.13 152 7408646 14.68 ug/L 97 22) Acenapthalene 18.66 153 4932656 16.95 ug/L 97 23) 2,4-Dinitrotoluene 19.27 165 954498 12.27 ug/L 91 24) Diethylphthalate 20.14 149 5412134 17.80 ug/L 99 25) 4-Chlorophenyl-phenylether 20.33 204 2613781 16.26 ug/L 99 26) Fluorene 20.20 166 5841726 17.55 ug/L 96 28) Azobenzene 20.78 77 6099480 15.20 ug/L 95 30) Nnitrosodiphenylamine 20.69 169 3084924 16.03 ug/L 94 31) 4-Bromophenyl-phenylether 21.76 248 1336488 17.25 ug/L 98 3 2) Hexachiorobenzene 21.79 284 1341308 18.09 ug/L 99 33) Phenanthrene 23.02 178 8046749 17.01 ug/L 96

(#) = qualifier out of range (m) = manual integration 501REFB.D 050102.M Thu May 09 13:48:51 2002 Page 1

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