GCMS analysis results, sample AE09974, May 2002

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Library Search Compound Report Data File C:\MSDCHEM\1\DATA\050602\9974.D Vial: 22 Acq On 7 May 2002 4:48 am Operator: Mclean Sample 4/25 Inst Instrumen Mise Multiplr: 1.00 MS Integration Params: LSCINT.e

Quant Method C:\MSDCHEM\1\METHODS\050102.M (Chemstation Integrator) Title 508 Modified GC/MS scan Library C:\DATABASE\NIST98.L Peak Number 6 3-Butenoic acid Concentration Rank 4 R.T. EstConc Area Relative to ISTD R.T. 34.98 0.34 ug/L 234434 Perylene-dl2 34.71 Hit# Of 5 Tentative ID MW MolForm CAS# Qual

1 3-Butenoic acid 86 C4H602 000625-38-7 4 2 Azetidine, 1-nitroso- 86 C3H6N2O 015216-10-1 4 3 4-Fluoro-3-nitrobenzotrifluoride 209 C7H3F4NO2 000367-86-2 3 4 Crotonic acid 86 C4H602 003724-65-0 2 Abundance Scan 5430 (34.984 min): 9974. D (-5428) (-) m/z 40.10 100.00% 43

5000

86 209 259 « i • ■ ■ * । ■ ■ ■ । 1 1 । । l ■ ■

+ 11 ■ । । ■ ■ । 11 I 118130 I — I । I I I | I I I I | I I I~I | I I I r | i 34.60 34.80 35.00 35.20 35.40 1 1 I ' ' | I |— 1 1 । ' 1 ' I ' 1 1 1 I 1 1 ' ' I ' 1 m/z 259.00 23.97% m/z-> 20 40 60 80 100 120 140 160 180 200 220 240 260 Abundance #1245: 3-Butenoic acid 3?

5000 -J. , . 1 }rt/BI 34.60 34.80 35.00 35.20 35.40 58 86 m/z 2 09.00 20.07% ........ I. . 72 ..................................................... । । । | । ll । । n n 1‘‘]U‘ ‘ i । । । । l 1‘|‘ ‘}II|IIII|I i i | i r m/z-> 20 40 60 80 100 120 140 160 180 200 220 240 260 Abundance #734: Azetidine, 1 -nitroso- 33

34.60 34 80 35.00 35.20 35.40 5000 86 m/ Z 85.90 19.84% 42

_a 55

TrTrr .6, "111/1,1/1/11/"/1/1/1-1/1T/T7"[711111.1111/11/1/-1/1/1/1/11/7/1/"/d/"//T-"/rTm-n m/z->______ 20 40 60 80 100 120 140 160 180 200 220 240 260 Abundance #999: 4-Fluoro-3-nitrobenzotrifluoride M TA AMAMMA AMM,A, 33 34.60 34.80 35.00 35.20 35.40 163 m/z 2 08.00 17.32% 209 5000 101113 143 63 75 179 50 | 125 193 18 1 1 i 1 1 I " 111L jl "ll 1 , 1 4871 4,170a , JI , tt I‘I". Jj' 1 ■ । 1 1 1 1 i ' ' 1 1 I_______ 1 1 1 ' I 1 ' apar MAr mryk r Awn Tl/Z-> 20 40 60 80 100 120 140 160 180 200 220 240 260 34.60 34.80 35.00 35.20 35.40

9974.D 050102.M Tue May 07 15:53:29 2002 Page 10

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