GCMS analysis results, sample AE09972, May 2002

NYC 9/11 Public Portal Document

Library Search Compound Report

Data File C:\MSDCHEM\1\DATA\050602\9972.D Vial: 20 Acq On 7 May 2002 3:11 am Operator: Mclean Sample 4/25 Inst Instrumen Mise Multiplr: 1.00 MS Integration Params: LSCINT.e Quant Method : C:\MSDCHEM\1\METHODS\050102.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Library : C:\DATABASE\NIST98.L ********************************************************************* Peak Number 7 Chloroacetic acid, hexyl ester Concentration Rank 3 R.T. EstConc Area Relative to ISTD R.T.

5.10 0.43 ug/L 351021 1,4-Dichlorobenzene-d4 9.94 Hit# of 5 Tentative ID MW MolForm CAS# Qual 1 Chloroacetic acid, hexyl ester 178 C8H15C1O2 1000131-85-3 2 Chloroacetic acid, 2-methylpropy... 150 C6H11C1O2 1000131-85-2 27 3 Ethanedioic acid, bis(1-methylpr... 202 C10H18O4 013784-89- 23 4 Butyl aldoxime, 2-methyl-, anti- 101 C5H11NO 049805- ,5-2 10 Abundance Scan 343 (5.094 min): 9972.D (-338) (-) m/ z 44.10 100.00% 44 fl 56

5000 35 72 86 129

T । । । । I । ! । । i । । i । i i । । j i r-i , । , i i । i r Mrp—n"wA ’111111 1111 * 1111* 4.80 5.00 W 5.20 5.40 ... 1 1 11 1 1 11 Th)l ' i ■ ■ ■ ■ । > I 11 m/z 41.10 87.86% m/z-> 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 Abundance 1#15104: Chloroacetic acid, hexyl ester 43 56

MM"w " — 5000 “1 0 I l l I "u I I 69 77 4.80 5.00 5.20 5.40 m/ z 56.10 82.05% 85 95 107 121 135 149 163 178 ■ ■ । ■ 11 +14 TTT I । । ' I r i । । i ; i j i > i i । । । । । । । । i । । '! i i । i i i i | i i । । । । ' । i । i ।

/z-> 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 Abundance #15033: Chloroacetic acid, 2-methylpropyl ester 56 41 77 1 1 1 i 1 1 1 1 1 1 1 4.80 5.00 !5.20 5.40 5000 m/z 57.10) 72.32% 108

1111 ‘ ‘11 mill 4— 69, ,, 85 TPTPT 95 I I | I I I rj । i r 123 135 I 1 ' 1 ■ । ■ ■ ■ ■! ■ ■ ■. । 150 । । । I 1 1 ' 1 ( /z->_____ 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 Abundance I I I | , ■ 1 I | I T I 1 | I I | I | L | | #15933: Ethanedioic acid, bis(1 -methylpropyl) ester 57 4.80 5.00 5.20 5.40 41 m/z 128.90 66.60% 5000

। 49 65 73 84 103 117 1 31 147 1111111 rW | । । । । |' i I r ) [ «‘ r I I । । । । । ।' I i i i | 1 i i' i | । । । । । ’ i i i k | '1 I I ‘r | I I I ! | I I I I | I I I I | | I 1 I ' 1 1 1 1 1 1 1 1 I 1 1 1 1 I ' 1 m/z-> 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 4.80 5.00 5.20 5.40

9972 .D 050102.M Tue May 07 15:50:58 2002 Page 11

NYC-WTC_000044016