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GCMS analysis results, sample AE12478, June 2002

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Laboratory report showing GCMS analysis results for sample AE12478 including surrogate recovery data on June 10, 2002.

NYC-WTC_000014460–000014484

Folder label: “GCMS X 5/28/02 A 5/29/02

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NYC 9/11 Public Portal Document

Library Search Compound Report Data File : C:\MSDCHEM\1\DATA\052902\12478.D Vial: 20 Acq On : 30 May 2002 1:34 am Operator: McLean Sample : gc/ms scan 5/28 Inst : Instrumen Mise Multiplr: 1.00 MS Integration Params: LSCINT.e Quant Method : C:\MSDCHEM\1\METHODS\052202.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Library : C:\DATABASE\NIST98.L ********************************************************************* Peak Number 1 Butanoic acid, methyl ester Concentration Rank 16 R.T. EstConc Area Relative to ISTD R.T. 3.47 0.21 ug/L 150926 1,4-Dichlorobenzene-d4 9.90 Hit# of 5 Tentative ID MW MolForm CAS# Qual 1 Butanoic acid, methyl ester 102 C5H10O2 000623-42-7 9 2 Phosphonic dichloride, (2,2-dime... 188 C5H11C12OP 054552-71-5 9 3 3,3-Dichloropropyne 108 C3H2C12 1000222-23-9 9 4 Butanoic acid, methyl ester 102 C5H10O2' 000623-42-7 9 Abundance Scan 67 (3.473 min): 12478.D (-62) (-) m/z 43.10 100.00% 43

5000

UZI 51 1 59 74

88 WN . । . . -r-i-[-T-r-r-r-]~r-r 3.20 3.40 3.60 3.80

A 01 1+ ‘ i “ “ i ‘ • ■ i ■11 i ■ ■1 • i ■ " ■ f ■ ‘ “ i ■ “ • i ■ “ ■ i ■' “ i ■ “ ■ i • ‘ “ i m/ z 74.10 72.41% niz-> 10 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 Abundance #109994: Butanoic acid, methyl ester 43 74

5000 I** t—r-[—r-r-r-r

27 3.20 3.40 3.60 3.80 15 59 m/z 72.12%

1 87

miz-> 01TImgu 1# + 102 •T“"!+ TIadtmua0u*mummTanOuTr 10 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 Abundance #24356: Phosphonic dichloride, (2,2-dimethylpropy!)- 43 71

320 3.40 3.60 3.80 5000 m/z 41.05 32.55%

vbuNw 27 55

m/z-> Ot 12" —354 I, rrtet | . . 63 i, 83 ’ha । n rl" i ri । I'd 11 101 117 * r1-1" । >11"*t 160 TTPmTTTTHT 10 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 Abundance #28312:3,3-Dichloropropyne ' ■ i ■ ■ • • i ■ • • ■ i 1 ■ ■ ' i • • ■ ■ 74 3.20 3.40 3,60 3.80

MwuGM"* m/z 87.95 32.55% 5000: 38 47 60 82 108 0 TTT — '■ i1 ■1 ■ i ■ ■ “ i ‘ ■11" ■ ■ i “ “ i •" • i11' ■ i ■ ■ i ■ “ ■ i m/z—> 10 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 3.20 3.40 3,60 3.80

12478.D 052202.M Mon Jun 03 11:40:25 2002 Page 4

NYC-WTC_000014468

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NYC-WTC_000014468Source: NYC Law Department, mirrored locally

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