GCMS surrogate recovery report, sample AE12283, June 2002

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Data File : C:\MSDCHEM\l\DATA\0610022\12283.D Vial: 11 Acq On : 10 Jun 2002 7:10 pm Operator: Sample : gc/ms scan 6/7 Inst : Instrumen Mise Multiplr: 1.00 MS Integration Params: LSCINT.e Quant Method : C:\MSDCHEM\1\METHODS\060302.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Library : C: \DATABASE\NIST98 . L ********************************************************************* Peak Number 1 Butanoic acid, methyl ester Concentration Rank 18

R.T. EstConc Area Relative to ISTD R.T.

3.48 0.35 ug/L 277894 1,4-dichlorobenzene-d4 9.90

Hit# of 5 Tentative ID MW MolForm CAS# Qual 1 Butanoic acid, methyl ester 102 C5H10O2 000623-42-7 50 2 Butanoic acid, methyl ester 102 C5H10O2 000623-42-7/50 3 Butanoic acid, methyl- ester 102 C5H10O2 000623-42 50 4 Butane, 2,2-dimethyl- 86 C6H14 000075-83-2 9 Abundance Scan 68 (3.479 min): 12283.D (-65) (-) m/z 43.05 100.00% 43 74

5000 49 59 87 36 । 3.20 3.40 3.60 3.80 0! 220 IL—+L1....... PI m/z 74.10 83.63% m/z-> 10 20 30 40 50 60 70 80 90 100 110 Abundance #109994: Butanoic acid, methyl ester 43 74

5000 27 3.20 3.40 3.60 3.80 15 59 m/z 71.10 62.25% 87

miz-> 0! ' ■ i '-I1' ■ i ■ 10 20 30 33 34, 1,1/53,4 T 40 50 69 70 60 80 ■ ■ i ■ ■ ■ 1 i ' ■ 90 102 TITTTT 100 110 Abundance #109995: Butanoic acid, methyl ester 43 f J 74 320 3.40 3.60 3.80 5000 27 m/z 59.10 25.19% 15 59 87 , .I .33 38 | 69 I 102 01 TTprf --- 1‘r 1531,-1 .... 170 80 *’1141 11/4/I a 90 100 110 miz-> 10 20 30 40 50 60 Abundance #109993: Butanoic acid, methyl ester 43 74 3.20 3.40 3.60 3.80 m/z 49.10 .24.82% 5000 27 59 87 69 102 0 ............ .. 111(53 nni ■ ' 1‘| I’IIIIII 1. miz-> 10 20 30 40 50 60 70 80 90 100 110 3.20 3.40 3.60 3.80

12283.D 060302.M Tue Jun 11 08:23:32 2002 Page 4

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