GCMS analysis results, sample AE09967, May 2002

NYC 9/11 Public Portal Document

Library Search Compound Report Data File C:\MSDCHEM\1\DATA\050602\9967.D Vial: 23 Acq On 7 May 2002 5:37 am Operator: Mclean Sample 4/25 Inst Instrumen Mise Multiplr: 1.00 MS Integration Params: LSCINT.e Quant Method : C:\MSDCHEM\1\METHODS\050102.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Library : C:\DATABASE\NIST98.L ********************************************************************* Peak Number 4 3-Methoxybut-l-ene Concentration Rank 6

R.T. EstConc Area Relative to ISTD R.T. 5.64 0.23 ug/L 173101 1,4-Dichlorobenzene-d4 9.94

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 3-Methoxybut-l-ene 86 C5H10O 017351-24-5 14 2 3-Methoxybut-l-ene 86 C5H10O 017351-24-5/9 3 2-Butene, 4-methoxy 86 C5H10O 018408-99-6 9 4 2-Butene, 1-methoxy-, (E)- 86 C5H10O 010034-14-7 9 Abundance Scan 436 (5.641 min): 9967. D (-428) (-) m/z 40.10 /100.00% 4 71 MNMWyWYww

43

5000 49 59 36 86 I 1 1 ' ' I ’ 1 ' ■ I 1 1 1 1 I 1 1 1 1 1 1 1 1 74 5.20 5.40 5.60 5.80 6.00 r 11 1 r ' . J , n — — TTTT m/z 71.10 97.19% mfe-> 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 Abundance #114479:3-Methoxybut-1 -ene 71 41

5000 29 55

59 86 ........II.....4 5.20 5.40 5.60 5.80 6.00 m/z 41.10 96.88% 45 38 51 II t I! 11 11 111111 ] * 1 ' | 1 1 > ■ | । i > i | 11 11 11 I n | i i i i | r 1 1 1 1 1 1 ' 1 1 I. ....... I m/z-> 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 Abundance #24260: 3-Methoxybut-1-ene 71 41 TPTTTPP1? 17 P I- 55 5.20 5.40 5.60 5.80 6.00 5000 m/z 39.10 72.81% 59 86

31 45 I 38 I I I I I I I I I I I I I I I I I I I I I H 11... . n1, h | L l p " ■ i ■ '1 11 #......-......H H 11 ■'111 1 m/z-> 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 Abundance #24258: 2-Butene, 4-methoxy I ‘ 1 ' I ' ' 1 ’’i''"' . . । t । । ITT r 71 5.20 5.40 5.60 5.80 6.00 m/z 43.10 66.41% 41 55 5000 29 86 45

m/z-> ' 111111 i1 20 25 30 ।1 ‘1 ■ ।1 35 38111,111151/1 40 45 50 55 60 65 70 75 80 58 I ! I I | I I '' I''111 i ■ ■ i ■ * ■ 11 ■ •

85 90 95 5.20 5.40 5.60 5.80 6.00

9967.D 050102.M Tue May 07 15:45:30 2002 Page 8

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