GCMS sample analysis results, AE11906, June 3, 2002

NYC 9/11 Public Portal Document Library Search Compound Report Data File : C:\MSDCHEM\1\DATA\052202\11906.D Vial: 13 Acq On : 22 May 2002 11:36 pm Operator: Mclean Sample : 5/21 ad Inst : Instrumen Mise : Multiplr: 1.00 MS Integration Params: LSCINT.e Quant Method : C:\MSDCHEM\1\METHODS\050102.M (Chemstation Integrator) Title : 508 Modified GC/MS scan 71 Library : C:\DATABASE\NIST98.L ********************************************************************* Peak Number 9 3-Methoxybut-l-ene Concentration Rank 10 R.T. EstConc Area Relative to ISTD R.T. 4.90 0.40 ug/L 311284 1,4-Dichlorobenzene-d4 9.90 Hit# of 5 Tentative ID MW- Mol Form CAS# ual

1 3-Methoxybut-l-ene 86 C5H10O 017351-24/5 38 2 1-Trifluoroacetoxy-2-methylpentane 198 C8H13F3O2 1000215-95-6 32 3 3-Methoxybut-l-ene 86 C5H10O 017351-24-5 25 4 2-Butene, 1-methoxy-, (E) -____________ 86 C5H10O 010034-14-7 16 Abundance Scan 310 (4.901 min): 11906.D (-307) (-) m/z 43.10 100.00% 43 71 MroAwo/loawta,,, 5000 55 39 59 51 86 - ' ■ i ■ ■ ■ ■ i • • ■ ■ i ' ■ ■ ■ i ■ ■ ■ ■ i 83 fr 1H 4.60 4.80 5.00 5.20

n/z-> 0: 20 25 30 35 40 45 50 55 60 65 70 111111/T a 75 80 TTTTTT 85 90 95 m/z 41.10 95.66% Abundance #114479:3-Methoxybut-1 -ene 71 41 55 "wyhwyryW/VAMMWorV 5000 29 59 ■ ■ ■ । • ■ ■ ■ । ‘ । ‘ । ■ ■ ■ ■ । 86 4.60 4.80 5.00 5.20 m/z 71.10 77.20%

miz-> 0 ■■i■■•■i■ 20 25 38 I " " I '' H | 30 35 +HH 45 51 | 40 45 50 55 60 65 70 75 80 | , ' i ‘ ■ i — 85 90 95 Abundance #6107:1-Trifluoroacetoxy-2-methylpentane 43 69 ■ ■ i ■ • ■ ■ i ■ i ■ ■ ■ ■ i ■ ■ • • i 4.60 4.80 5.00 5.20 5000 55 m/z 69.10 65.15%

51 84 39

miz-> Of - 11 ■ “ ■ 1 ■11 47 11 + ,59 . ......... t 11 “ 111' ■ i •1 11, i 11

20 25 30 35 40 45 50 55 60 65 70 75 83 85 90 95 72

Abundance #24260:3-Methoxybut-1-ene ■ * ■ i ■ ■ ■ ■ i ■ ■ 1 1 i ■ • ' ■ i ■ ■ ■ • i 71 4.60 4.80 5.00 5.20 41 m/z 55.10 43.24% 55 5000 59 86

■ntz~> 31 I 38 o- ‘ * 11 ’ ' ■ i ■' “ i1'" 111 n । 20 25 30 35 40 + 4445

45 —H+ 51 50 55 11 11' I" " I' 60 65 70 75 80 -PPP 85 90 95 4.60 4.80 •I ■ ■ • • । • • ■ > । 5.00 5.20

11906.D 052202.M Tue May 28 12:13:19 2002 Page 12

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