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GCMS calibration table, April 24, 2002

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Calibration table for GC/MS analysis listing deuterated standards and their response values from April 24, 2002.

NYC-WTC_000043678–000043685

Folder label: “GCMS X 4/24/02 A 5/3/02

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NYC 9/11 Public Portal Document

Data File : C:\HPCHEM\1\DATA\APR2302\8838.D Vial: 7 Acq On : 23 Apr 2002 8:17 pm Operator : Sample : gc/ms scan 4/15 Inst : 209 Mise : Multiplr: 1.00 MS Integration Params: GOOFY.P Quant Time: Apr 24 8:16 2002 Quant Results File: GCMS0412.J Quant Method : C:\HPCHEM\1\METHODS\GCMS0412.M (RTE Integrator) 3 Title : 209 625/TCLP calibration table 111 A Last Update : Wed Apr 17 11:48:30 2002 N i l Response via : Initial Calibration M 0 , W DataAcq Meth : GCMS0412 V XP

Internal Standards R.T. Qlon Response Cone Units Dev(Min)

1) 1,4-Dichlorobenzene-d4 12.21 152 556961 20.00 ug/1 -0.03 10) Naphthalene-d8 15.84 136 2033760 20.00 ug/1 -0.03 17) Acenaphthene-dlO 21.15 164 1155302 20.00 ug/1 -0.02 30) Phenanthrene-diO 25.59 188 1707097 20.00 ug/1 -0.02 39) Chrysene-dl2 33.64 240 1065452 20.00 ug/1 -0.03 45) Perylene-dl2 37.88 264 645036 20.00 ug/1 -0.04

System Monitoring Compounds 2 8) TCMX 23.29 209 38850 6.71 ug/L -0.04 Spiked Amount 10.000 Recovery = 67.10% 38) 2,4-DDD 0.00 235 0 0.00 ug/mL Spiked Amount 5.000 Recovery = 0.00%

Target Compounds Qvalue 2) N-nitroso-dimethyl amine 0.00 74 0 N.D. 3) bis(2-Chloroethyl)ether 0.00 93 0 N.D. 4) 1,3-Dichlorobenzene 0.00 146 0 N.D. 5) 1,4-Dichlorobenzene 0.00 146 0 N.D. 6) 1,2-Dichlorobenzene 0.00 146 0 N.D. 7) 2,2'-oxybis(1-Chloropropan 0.00 45 0 N.D. 8) N-Nitroso-di-n-propylamine 0.00 70 0 N.D. 9) Hexachloroethane 13.87 117 176 N.D. 11) Nitrobenzene 0.00 77 0 N.D. 12) Isophorone 0.00 82 0 N.D. 13) bis(2-Chloroethoxy)methane 0.00 93 0 N.D. 14) 1,2,4-Trichlorobenzene 0.00 180 0 N.D. 15) Naphthalene 15.91 128 1085 N.D. 16) Hexachlorobutadiene 0.00 225 0 N.D. 18) Hexachlorocyclopentadiene 0.00 237 0 N.D. 19) 2-Chloronaphthalene 0.00 162 0 N.D. 20) Dimethylphthalate 0.00 163 0 N.D. 21) 2,6-Dinitrotoluene 0.00 165 0 N.D. 22) Acenaphthylene 0.00 152 0 N.D. 2 3) Acenaphthene 0.00 153 0 N.D. 24) 2,4-Dinitrotoluene 21.42 165 111 N.D. 25) Diethylphthalate 22.63 149 266 N.D. 26) 4-Chlorophenyl-phenylether 0.00 204 0 N.D. 27) Fluorene 0.00 166 0 N.D. 29) Azobenzen/ 1,2-Diphenylhyd 0.00 77 0 N.D. 31) N-Nitrosodiphenylamine 0.00 168 0 N.D. 32) 4-Bromophenyl-phenylether 0.00 248 0 N.D.

(#) = qualifier out of range (m) = manual integration 8838 .D GCMS0412.M Wed Apr 24 08:17:44 2002 Page 1

NYC-WTC_000043678

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