GCMS calibration report, May 6, 2002

NYC 9/11 Public Portal Document QuclI—AL LCU Ll RCDUL U

Data File C:\HPCHEM\l\DATA\MAY0602\CAL160.D Vial: 2 Acq On 6 May 2002 10:29 am Operator: Sample Inst : 209 Mise Multiplr: 1.00 MS Integration Params: GOOFY.P Quant Time: May 8 8:31 2002 Quant Results File: GCMS0501.RES

Quant Method : C:\HPCHEM\1\METHODS\GCMS0501.M (RTE Integrator) Title : 209 625/TCLP calibration table Last Update : Wed May 01 10:40:31 2002 Response via : Initial Calibration DataAcq Meth : GCMS0501

Internal Standards R.T. Qlon Response Cone Units Dev(Min)

1) 1,4-Dichlorobenzene-d4 12.19 152 465695 40.00 ug/1 -0.02 10) Naphthalene-d8 15.84 136 1691393 40.00 ug/1 -0.01 17) Acenaphthene-diO 21.14 164 898133 40.00 ug/1 -0.01 30) Phenanthrene-diO 25.58 188 1291538 40.00 ug/1 -0.01 38) Chrysene-dl2 33.66 240 860161 40.00 ug/1 -0.01 44) Perylene-dl2 37.87 264 510513 40.00 ug/1 -0.01

System Monitoring Compounds 28) TCMX 23.28 209 43243 9.89 ug/L -0.01 Spiked Amount 10,000 Recovery = 98.90%

Target Compounds 1(2- 203 Qvalue 2) N-nitroso-dimethyl amine 5.86 74 1857629 145.89 ug/1 97 3) bis(2-Chloroethyl)ether 11.60 93 2419357 146.48 ug/1 94 4) 1,3-Dichlorobenzene 12.10 146 2358933 162.54 ug/1 98 5) 1,4-Dichlorobenzene 12.25 146 2534940 159.82 ug/1 99 6) 1,2-Dichlorobenzene 12.76 146 2225153 161.82 ug/1 99 7) 2,21-oxybis(1-Chloropropan 13.08 45 4516767 132.30 ug/1 97 8) N-Nitroso-di-n-propylamine 13.49 70 1729631 139.73 ug/1 96 9) Hexachloroethane 13.61 117 902950 151.57 ug/1 91 11) Nitrobenzene 13.90 77 2252732 146.23 ug/1 93 12) Isophorone 14.54 82 4245030 142.14 ug/1 95 13) bis(2-Chloroethoxy)methane 15.23 93 2760276 145.63 ug/1 99 14) 1,2,4-Trichlorobenzene 15.73 180 1941299 169.45 ug/1 98 15) Naphthalene 15.91 128 5508704 155.56 ug/1 99 16) Hexachlorobutadiene 16.44 225 905443 172.03 ug/1 99 18) Hexachlorocyclopentadiene 18.63 237 890241 195.60 ug/1 100 19) 2-Chloronaphthalene 19.41 162 3230931 162.91 ug/1 98 20) Dimethylphthalate 20.52 163 4055445 160.63 ug/1 100 21) 2,6-Dinitrotoluene 20.74 165 987124 179.97 ug/1 92 22) Acenaphthylene 20.68 152 5608999 157.16 ug/1 99 23) Acenaphthene 21.25 153 3324739 158.79 ug/1 99 24) 2,4-Dinitrotoluene 21.90 165 1102737 187.50 ug/1 89 25) Diethylphthalate 22.65 149 3595751 157.01 ug/1 99 26) 4-Chlorophenyl-phenylether 22.79 204 1759384 162.40 ug/1 97 27) Fluorene 22.77 166 3464615 155.23 ug/1 99 29) Azobenzen/ 1,2-Diphenylhyd 23.26 77 4521816 146.97 ug/L # 92 31) N-Nitrosodiphenylamine 23.19 168 1205665 140.80 ug/1 # 90 32) 4-Bromophenyl-phenylether 24.25 248 1087315 173.30 ug/1 95 33) Hexachlorobenzene 24.69 284 1238821 176.80 ug/1 98 34) Phenanthrene 25.67 178 4984802 159.25 ug/1 99

(#) = qualifier out of range (m) = manual integration CAL160.D GCMS0501.M Wed May 08 08:31:19 2002 Page 1

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