TCLP calibration table review document, April 2002

NYC 9/11 Public Portal Document

Library Search Compound Report

Data File : C:\HPCHEM\l\DATA\APR1702\8209.D Vial: 20 Acq On : 18 Apr 2002 2:46 am Operator: Sample : gc/ms scan 4/8 Inst : 209 Mise Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\HPCHEM\1\METHODS\GCMS0412.M (RTE Integrator) Title : 209 625/TCLP calibration table Library : C:\DATABASE\NBS75K.L

Peak Number 1 1,1,1,5,7,7,7-Heptamethyl-3,3 - Concentration Rank 5 R.T. EstConc Area Relative to ISTD R.T. 37.31 0.50 ug/1 82855 Perylene-dl2 37.88 Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 l,l,l,5,7,7,7/-Heptamethyl-3,3-bis(t 444 C13H40O5Si6 038147-00-1 37 2 Trisiloxane,/l,1,1,5,5,5-hexamethyl 384 C12H3604Si5 003555-47-3 22 3 3-Trimethylsilyloxystearic acid, tr 444 C24H52O3Si2 000000-00-0 12 4 Noradrenaline, tetra-TMS 457 C20H43NO3Si4 000000-00-0 10 Abundance Scan 3514 (37.308 min): 8209. D (-) m/ z 73.00 100.00% 73

5000 147 221 281 355 429 ~i । j । l i [ ।' । । । । i~। । । । Ll 1l [

44, > 1196 119 । i' .1 "i 11 ) । 11 । 11 । 11 । T111 177 3 I I' "1... 401, li 253 । ii II I , | 325 ii L i । । । । 1 1 1 । 'i ' r| r । 11 । । । । T । । । i । । i t । । I ’ I "111"111" " I 37.00 37.20 37.40 37.60 m/z 147.00 49.01% m/z~> 40 60 80 100120140160180200220240260280300320340360380400420 Abundance #56714:1,1,1,5,7,7,7-Heptamethyl-3,3-bis(trimethylsiloxy)t 73

147 5000 267 1 ' 1 * 1 ' 1 1 355 37.00 37.20 37.40 37.60 429 45 207 m/z 221.00 44.95% 111..... L " ।11" । 11 11 1111 erpm II I I I I I I I [ I I I I I I I I I I I I I I I T I T‘ 1 ‘r I ' r '(' i " " r n 11' "r mfe-> 40 60 80 100120140160180200220240260280300320340360380400 420 Abundance #52459: Trisiloxane, 1,1,1,5,5,5-hexamethyl-3,3-bis[(trimet 73 147 ।Ii [ i । ।I | I I I 1] Ti II | r'I I r | I 281 37.00 37.20 37.40 37.60 5000 m/z 355.05 30.54%

369 207 i ’" ' [' j r 1111" 111" " i T’’ ri I 11T" I' 111111" '' 11" 11'1 H '11 ‘ I ‘11111" ' I 249.1........338.... It 12102971111 m/z-> 40 60 80 100120140160180 200220240260280300320340360380400420 Abundance #56734:3-Trimethylsilyloxystearic acid, trimethylsilyl est A

D •1IImi i [ I i i । | । f I r"।' i 1 1 ' I 73 37.00 37.20 37.40 37.60 m/z 281.00 27.83% 5000 147 233

313 429

I I I I I II I I I I I I I I I I I I I I I I I I I I I I 1 1 I 189 HH L II" | " " | 1 " ’ | ...339 387 — T T l | i ‘ I I [ I I-1 | I t i I | I I I I [

m/z-> 40 60 80 100120140160180 200220240260 280300 320 340360 380 400420 37.00 37.20 37.40 37.60

8209.D GCMS0412.M Thu Apr 18 14:11:05 2002 Page 1

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