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GCMS surrogate recovery data for sample AE04945, April 2002

Machine-extracted title · confidence 100%

Record of surrogate compound recovery rates for sample AE07634 analyzed on April 30, 2002.

NYC-WTC_000040212–000040229

Folder label: “GCMS X 4/3/02 A 4/10/02

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NYC 9/11 Public Portal Document Library Search Compound Report

Data File : C:\MSDCHEM\1\DATA\020410\04945.D Vial: 11 Acq On : 10 Apr 2002 7:47 pm Operator: Nefliu Sample : sample Inst : Instrumen Mise Multiplr: 1.00 MS Integration Params: LSCINT.e

Quant Method : C:\MSDCHEM\1... \SCANAPR0902. M (Chemstation Integrator) Title : Method 508 GC/MS Scan Library : C:\DATABASE\nist98.1 ********************************************************************* Peak Number 4 HH-Dibenzo [b, E] [1,4] diazep. . . Concentration Rank 2

R.T. EstConc Area Relative to ISTD R.T.

14.69 0.23 ug/1 199484 Naphthalene-d8 15.77

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 HH-Dibenzo[b,E] [1,4] diazepin-11. . . 267 C16H17N3O 013450-73-2 2 2 Ethyl 4-chloro-3 -trif.luoromethyl. . . 267 C10H9C1F3NO2 018585-06-3 2 3 Benzoic acid, 2-[(trimethylsilyl ... 282 C13H2203Si2 003789-85-3 2 4 Stearic acid, 2-hydroxy-1-methyl... 356 C22H4403 014251-39-9 1 Abundance Scan 1976 (14.689 min): 04945.D (-1969) (-) m/ z 73.10 100.00% 70

5000 355 267

40 ' ' I ' ' ‘ ' I ' ' ' ' I ‘ ' I ' ' 14.40 14.60 14.80 15.00 0- i" ■' i" 111" " i " " r 11' i111 ■ i " " i " 11111 ‘11" " i' " ■ i " " i' " 1111" r 1" i " " 1111 11 m/z 355.10 41.51% m/z--> 0 20 40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 340 360 Abundance #955:11 H-Dibenzo[b,E][1,4]diazepin-1 1-one, 5-(3-aminoprop... 33 1 8 57 77 181 267 223

5000 249 ■ ■ I ' ■ ■ > I ■ ■ TT ' 1 1 1 I ' 1 14.40 14.60 14.80 15.00 97 154 m/z 266.90 37.96%

O—m 7 " i" i ■ ■1 ■ r■ "i'1 ■11' m/z—> 0 20 40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 340 360 Abundance #637: Ethyl 4-chloro-3-trifluoromethylcarbanilate 29

14.40 14.60 14.80 15.00 5000 195 m/z 40.00 14.93% 221 267 | 4 f 4 J 4 88 113 — qll 1475, ) 4 1 248 . m/z-> 0- 4.4 0 20 40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 340 360 ' "I ■ 11 " i" " i M 111" " 1111111

Abundance #115268: Benzoic acid, 2-[(trimethylsilyl)oxy]-, trimethyl... 73 14.40 14.60 14.80 15.00

5000 267

45

m/z-> 0 ...2028.401460 . 1.8091.100115120135152.175193210 0 233250 k.. * n 11 n 11’77 TT TT । r ] jii 1117 1, 11111’0110111//1111 TTT i । 140 160 180 200 220 240 260 280 300 320 340 360 i' "' r “ 1111'11'

04945.D SCANAPR0902.M Thu "Apr 11 14:06:56 2002 Page 6

NYC-WTC_000040221

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NYC-WTC_000040221Source: NYC Law Department, mirrored locally

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