GCMS reference scan results for sample AE00364, March 21, 2002

NYC 9/11 Public Portal Document

4 Quantitation Report (QT Reviewed)

Data File : C:\MSDCHEM\1\DATA\031902\220REF1.D Vial: 6 Acq On : 19 Mar 2002 3:46 pm Operator: McLean Sample : RE-INJ 2/20 Inst : Instrumen Miso Multiplr: 1.00 MS Integration Params: BENZO.P Quant Time: Mar 21 11:52:58 2002 Quant Results File: 5080302.RES

Quant Method : C:\MSDCHEM\l\5973N\5080302.M (RTE Integrator) Title : Quantitation For Method 508gcscan Last Update : Thu Mar 14 13:02:27 2002 Response via : Initial Calibration DataAcq Meth : 508SCAN

Internal Standards R.T. Qlon Response Cone Units Dev(Min)

1) 1,4-Dichlorobenzene-d4 9.54 150 1373915 20.00 ug/L 0.00 10) Naphthalene-d8 13.03 136 3571414 20.00 ug/I» 0.00 17) Acenaphthene-diO 18.13 164 1998446 20.00 ug/L 0.00 29) Phenanthrene-diO 22.50 188 3130538 20.00 ug/L 0.00 38) Chrysene-dl2 30.31 240 2906226 20.00 ug/L 0.00 44) Perylene-dl2 34.18 264 1700308 20.00 ug/L 0.00

System Monitoring Compounds 37) 2,4-ddd surr 27.43 235 268947 7.20 ug/L 0.00 Spiked Amount 5.000 Recovery = 144.00%

Target Compounds Qvalue 2) N-nitroso-dimethyl amine 3.59 74 159257 5.16 ug/L 100 3) bis(2-chloroethyl) ether 8.98 93 453997 9.34 ug/L 84 4) 1,3 - Dichlorobenze 9.38 146 368579 7.66 ug/L 100 5) 1,4 - Dichlorobenzene 9.59 146 389464 8.12 ug/L 98 6) 1,2 - Dichlorobenzene 9.96 146 399814 9.00 ug/L 99 7) 2,2 ‘ - oxybis (l-Chloropr 10.42 45 1148867 10.37 ug/L 98 8) N-Nitroso-di-n-propylamine 10.75 70 370733 10.60 ug/L 99 9) Hexachloroethane 10.86 117 120782 6.70 ug/L 90 11) Nitrobenzene 11.10 77 493554 7.67 ug/L 96 12) Isophorone 11.81 82 1195851 10.10 ug/L 98 13) bis(2-Chloroethoxy) methan 12.55 93 589765 8.28 ug/L 99 14) 1,2,4-Trichlorobenzene 12.90 180 327693 8.01 ug/L 97 15) Naphthalene 13.08 128 1364813 9.20 ug/L 99 16) Hexachlorobutadiene 13.53 225 121478 5.31 ug/L 100 18) Hexachlorocyclopentadiene 15.61 237 57058 3.24 ug/L 99 19) 2-chloronaphthalene 16.51 162 799539 8.76 ug/L 99 20) Dimethylphthalate 17.59 163 1138735 10.46 ug/L 100 21) 2,6-Dinitrotoluene 17.70 165 201005 8.67 ug/L 98 2 2) Acenaphthylene 17.69 152 1280236 10.12 ug/L 99 2 3) Acenaphthene 18.22 153 859986 9.99 ug/L 98 24) 2,4-Dinitrotoluene 18.85 165 277266 8.35 ug/L 96 25) Diethylphthalate 19.72 149 1089094 11.62 ug/L 99 26) 4-Chlorophenyl-phenyl ethe 19.89 204 519762 10.41 ug/L 96 27) Fluorene 19.76 166 1118657 11.03 ug/L 98 2 8) Azobenzen/ 1,2-Diphenylhyd 20.34 77 1306996 9.46 ug/L 99 30) N-Nitrosodiphenylamine 20.26 169 539996 8.03 ug/L 98 31) 4-Bromophenyl-phenyl ether 21.32 248 299714 10.85 ug/L 92 32) Hexachlorobenzene 21.34 284 316437 10.86 ug/L 97 33) Phenanthrene 22.56 178 1590896 10.97 ug/L 99 34) Anthracene 22.70 178 1487734 10.34 ug/L 100 35) Di-n-butylphthalate 24.65 149 1899467 11.43 ug/L 99 36) Fluoranthene 26.06 202 1863050 11.31 ug/L 98 39) Pyrene 26.69 202 1917538 9.54 ug/L 97 40) Butylbenzylphthalate 29.04 149 803572 9.34 ug/L 95 41) Benzo (a) antracene 30.29 228 1524641 10.00 ug/L 99 42) Bis (2-ethylhexyl) phthala 30.91 149 1107752 9.74 ug/L 97 43) Chrysene 30.38 228 1633923 11.27 ug/L 100 45) Di-n-Octylphthalate 32.75 149 1466176 8.03 ug/L 100 46) Benzo (b) fluoranthene 33.23 252 1247233 10.41 ug/L 99

(#) = qualifier out of range (m) = manual integration 220REF1.D 5080302.M Thu Mar 21 11:53:10 2002 Page 1

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