GCMS analysis results, sample AE03616, March 2002

NYC 9/11 Public Portal Document Library Search Compound Report . Data File : C:\MSDCHEM\1\5973N\02MAR08\0316.D Vial: 6 Acq On : 8 Mar 2002 7:42 pm Operator: Sample : 508 scan Inst : Instrumen Mise : March 8, 2002 Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\MSDCHEM\1...\HP022102. M (RTE Integrator) Title : 508 scan method Library : C:\DATABASE\WILEY7N.L

Peak Number 6 Butenol, methyl- Concentration Rank 4

R.T. EstConc Area Relative to ISTD R.T.

5.02 0.17 ug/L 105771 1,4-Dichlorobenzene-d4 9.71

Hit# of 5 Tentative ID MW MolForm CAS# Qual 1 Butenol, methyl- 86 C5H10O 060766-00-9 64 2 3-Buten-2-ol, 2-methyl- 86 C5H10O 000115-18-4 !50 3 3-hydroxy-4,4-dimethyl .gamma. B... 130 C6H10O3 052126-90-6 45 4 2-Furanmethanol, tetrahydro- (CA... 102 C5H1O02 000097-99-4 45 Abundance Scan 146 (5.022 min): 03516.D (-) m/z 71.00 100.00% 43 7h

5000 59 55 LAAA 4.60 4.80 5.00 5.20 ■ ■ i 1 ‘ 5.40

m/z—> 0- ----- 4 — ld i 84 51 tt+t 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 i 67 i ' ‘।। । ■ ■ • ■ ।■ t m/z 43.05 84.66% Abundance #4093: Butenol, methyl- 43 71

5000 59 I * * ’ ‘ i • ‘ 1 I • ‘ ‘ * I T 27 4.60 4.80 5.00 5.20 5.40 15 31 m/z 41.10 64.81% 53 1 86 67, m/z—> 0 5 " i1 ■ 'I... + t Tuupaagtutui 1’1’11311 "II ‘ 11111/111 1( 15 20253035404550556065 70 75 868590 ,-rrTT Abundance #4083: 3-Buten-2-ol, 2-methyl- 71 43 , 4.60Aha4.80AA5.00A45.20A 5.40 5000i m/z 69.10 39.97% 59 27 31 53

miz-> —37 -HHH Or■ > • > । " i • ■ ■ ‘ i' “11 ■ ’i. 5 10 15 2025303540455055606570 75 808590 , —nupmguuaDT] Tup 86

Abundance #26149: 3-hydroxy-4,4-dimethyl .gamma. Butanolactone $$ Pa... ■ ■ । ■ ■ • ■ । ■

43 7h 4.60 4.80 5.00 5.20 5.40 m/z 59.00 36.48% 5000 57 31 53 0bmmmmmmm 1. 4l.. . H 68 i" u i A -A - miz—> 5 10 15 20253035404550556065 70 75 808590 4.60 4.80 5.00 5.20 5.40

03516.D HP022102.M Fri Mar 15 10:09:35 2002 Page 8

NYC-WTC_000037791