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GCMS analysis results for sample AD29670, Jan 2002

Machine-extracted title · confidence 100%

GCMS analysis report for sample AD29670 listing unknown compounds and surrogate recovery data from January 28, 2002.

NYC-WTC_000036842–000036859

Folder label: “GCMS X 12/7/01 A 1/2/02

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Scanned page image, NYC-WTC_000036854
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NYC 9/11 Public Portal Document

Library Search Compound Report

Data File C:\HPCHEM\l\DATA\JAN0302\29670.D Vial: 15 Acq On 4 Jan 2002 12:13 am Operator: 209 GALOS Sample gems scan 12/7 Inst : GC/MS 209 Mise Multiplr: 1.00 MS Integration Params: LSCINT.P

Quant Method : C:\HPCHEM\1\METHODS\GCMS1126.M (RTE Integrator) Title : 209 625/TCLP calibration table Library : C:\DATABASE\NBS75K.L

Peak Number 6 Cyclopentasiloxane, decamethyl Concentration Rank 3

R.T. EstConc Area Relative to ISTD R.T.

14.16 0.88 ug/1 497134 Naphthalene-d8 15.13

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 Cyclopentasiloxane, decamethyl- 370 C10H3005Si5 000541-02-6 50 2 Benzoic acid, 2,5-bis(trimethylsilo 370 C16H30O4Si3 003618-20-0 47 3 3,4-Dihydroxybenzyl alcohol, tris (tr 356 C16H3203Si3 068595-79-9 46 4 Ben ic acid, 2,6-bis[(trimethylsil 370 C16H30O4Si3 003782-85-2 40 •Abundance Scan 993 (14.164 min): 29670.D (-) m/ z 73.00 100.00% 73

5000 267 355 . ........................................... — 45 13.80 14.00 14.20 14.40 1 , 89 108 133 154 177 193208223 251 + , 1 293 111323 339 T TIUunmnuumOOTTT TI m/ z 267.00 30.36% miz-> 40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 340 360 'Abundance #51266: Cyclopentasiloxane, decamethyl- 73

355 267 \ 5000 l-r 13.80 14.00 14.20 14.40 m/z 355.05 21.46% i'11' I i• ‘ 'i 191207 ' ’ ’' I' •' ’ I 251 i ‘1■' i'1' ■ i 323 339 TTTTT i ■ ■'' i m/z-> 40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 340 360 (Abundance #<3978: Benzoic acid, 2.5-bis(trimethylsiloxy)-, trimethyls 73 355 J 1TT ■ i * ■ ■ ■ i ' 13.80 14.00 14.20 14.40 5000 m/z 74.0.0 8.67% 45 . 147 179 207 223 267282297 j 370 i' • " r • " i • ’" i • • ” r • ” TTTTTTT r ■ " i' •1' i •" ■ i ■ ■ " r ■ ■ • i" ■' i m/z-> 40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 340 360 'Abundance #49868: 3,4-Dihydroxybenzyl alcohol, tris(trimethylsilyl)- 73 13.80 14.00 14.20 14.40 m/z 356.05 8.22% 267 5000 179 356 45 147 _................ I . | ll ! > | I . I I ( I t M p i l ! | i i 209 237 , ITTT । i i i . j i .7. | iYi . 312 341 , TT’T Pi | I I I l p I T‘‘‘II ........ 4......... m/z-> 40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 340 360 13.80 14.00 14.20 14.40

29670.D GCMS1126.M Wed Jan 16 14:50:51 2002 Page 6

NYC-WTC_000036854

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NYC-WTC_000036854Source: NYC Law Department, mirrored locally

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