GCMS analysis results for sample AD29523, Jan 2002

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Library Search Compound Report

Data File : C:\HPCHEM\l\DATA\DEC2701\29523.D Vial: 37 Acq On : 29 Dec 2001 12:10 am Operator: 209 GALOS Sample : GC/MS SCAN 12/7 Inst . : GC/MS 2 09 Mise : Multiplr: 1.00 MS Integration Params: LSCINT.P

Quant Method C:\HPCHEM\1\METHODS\GCMS1126.M (RTE Integrator) Title 209 625/TCLP calibration table Library C : \DATABASE\NBS75K . L ********************************************************************* Peak Number 4 Cyclohexasiloxane, dodecamethy Concentration Rank 2

R.T. EstConc Area Relative to ISTD R.T.

17.45 2.32 ug/1 1409540 Naphthalene-d8 15.29

Hit# Of 5 Tentative ID MW MolForm CAS# Qual

1 Cyclohexasiloxane, dodecamethyl- 444 C12H3606Si6 000540-97-6 38 2 2H-1,4-Benzodiazepin-2-one, 7-chlor 342 C18H19ClN2OSi 055299-24-6 22 3 Silane, {1,2,3-benzenetriyltris(oxy 342 C15H30O3Si3 017864-23-2 10 4 1,1,1,5,7,7,7-Heptamethyl-3 ,3-bis(t 444 C13H40O5Si6 038147-00-1 9 Abundance Scan 1352 (17.453 min): 29523.D (-) m/ z 73.00 100.00% 73

5000 341 ................... ........................ 147 429 45 17.20 17.40 17.60 17.80

m/z-> mh | 96 117 | 179 207225 251 281 311 , 'i । n ., ।,,, r ।.. r,,, h, ।.,.. ।., r, ।, I., ।,,, < ।, fi. ।, i,. ।,,.. ।,, ■>, । A 40 60 80 100120140160180 200 220 240 260 280 300 320 340 360 380400420 1 397 I ‘1' 'I TTTT , m/ z 3 41.0.0 31.70% Abundance #56711: Cyclohexasiloxane, dodecamethyl- 73 341

5000 429 _ - 17.20 17.40 17 60 17.80 147 m/z 147.00 14.62% 117 |. 207 I"EEII"I"TETTTT PPIT r '" r "' r "' i" " i 267 I’‘ ’I 11n11n u (I. । < । <... । l" "I"''I' 311 1 1...... m/z- > 40 60 80 100120140160180 200220 240260280 300 320 340 360 380 400420 Abundance #48337: 2H-1.4-Benzodiazepin-2-one, 7-chioro-1,3-dihydro-5- 73 341 i / l ■ 17.20 17.40 17.60 17.80 5000- m/z 342.0.0 10.86% 45 | 91 i ! 116 146 227 269 315 . _______ i i p i i i p i i i p n i pi i i | TCTTTTT p.i.pn.Yi. npn.pn.p.i.pn.p

m/z-> 40 60 80 100120140160180 200 220 240 260280 300 320 340 360 380400 420 Abundance #48324: Silane, [1,2,3-benzenetriyltris(oxy)]tris[trinnethyl- _ ................ 1 1 r■ • ■ I 1 1 1 1 I 1 ' 73 17.20 17.40 17.60) 17.80

239 m/z 429.05 10.10% 5000- 342

45 133 I 179 211 "' r " ‘ i"1' i" " r "' i"'' i"'' i" "I ■ ■" I' TTTTTT..... 111111111111 314.4 "IIEEIITETO’ITIT / V_____________ TtET I I I I I ! I I I m/z-> 40 60 80 100120140160180 200 220 240 260 280 300 320 340 360 380 400 420 17.20 17.4G 17.60 17.80

29523.D GCMS1126.M Tue Jan 08 12:09:37 2002 Page 4

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