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GCMS analysis results for sample AD29522, Jan 2002

Machine-extracted title · confidence 100%

Quality reviewed GCMS data listing surrogate compounds and retention times from January 3, 2002.

NYC-WTC_000036752–000036778

Folder label: “GCMS X 12/7/01 A 1/2/02

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Scanned page image, NYC-WTC_000036770
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NYC 9/11 Public Portal Document

Library Search Compound Report

Data File C:\HPCHEM\l\DATA\DEC3101\29522.D Vial: 63 Acq On 3 Jan 2002 3:00 am Operator: 209 GALOS Sample gems scan 12/7 Inst : GC/MS 209 Mise Multiplr: 1.00 MS Integration Params: LSCINT.P

Quant Methpd : C:\HPCHEM\1\METHODS\GCMS1126.M (RTE Integrator) Title : 209 625/TCLP calibration table Library : C:\DATABASE\NBS75K.L ********************************************************************* Peak Number 13 Methyl 12-ketomethylpodocarpat Concentration Rank 18

R.T. EstConc Area Relative to ISTD R.T.

32.26 5.10 ug/1 10635200 Chrysene-dl2 33.05

Hit# Of 5 Tentative ID MW MolForm CAS# Qual

1 Methyl 12 -ketomethylpodocarpate 302 C19H2603 001231-74-9 10 2 Estra -1,3 ,5(10) -triene -16,17-diol, 302 C19H26O3 001474-53-9 10 3 1,2 : 3,4 -Dibenzpyrene 302 C24H14 000000-00-0 9 4 1,2:4,5-Dibenzpyrene 302 C24H14 000000-00-0 9 Abundance Scan 2964 (32.259 min): 29522.D (-) m/z 287.10 100.00% ! 287

5000 209 105 165 - 77 ■ ■ I > >

miz-> 4144447 11.1 40 60 80 10 239 269 3)4 396 Tt " r " ■ i' ‘■ i ■ ■" i'" ' r '" r' 120 140 160 180 200 220 240 260 280 300 320 340 360 380 400 32.00 32.20 32.40 32.60 m/z 302.15 . 59.80% Abundance #43132: Methyl 12-ketomethylpodocarpate 227 302

-----------------I-- 5000 32.00 32.20 32.40 32.60 171 m/z 209.10 47.91% ।... 11 . ।. q nn । r. . i । > । 11 । T1198 ’TTTTTTCTITTTTT"T’’T TTp-m | "ItTpTTTp-r’ 0’1"IT"IIIIT > m/z-> 40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 340 360 380 400 Abundance #43140: Estra-1,3,5(10)-triene-16,17-diol, 3-methoxy-, (16. 302

32.00 32.20 32.40 32.60 5000 m/z 105.05 29.32% 160 , 186 215 284' | i h l l 2 Tp-n-rp I I > | r> > I | I tt, ( . r > ! (>-, n । > > > < (Trrrpi m/z~> 40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 340 360 380 400 Abundance #43230: 1,2:3,4-Dibenzpyrene 1 ■ i ' ■ m-r-p-r 302 32.00 32.20 32.40 32.60 m/z 223.1.0 27.32% 5000

151 125. J 274 i1" ’ r1" i TOTTTTTTTTTTUTTTT 11 ■'' 11 i" ,l I TTT i" " I •“Ip' TI ' 1 m/z-> 40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 340 360 380 400 32.00 32.20 32.40 32.60

29522.D GCMS1126.M Fri Jan 18 16:49:05 2002 Page 13

NYC-WTC_000036770

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NYC-WTC_000036770Source: NYC Law Department, mirrored locally

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