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GCMS analysis results for sample AD29563, Jan 2002

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GCMS analysis report for sample AD29563 listing unknown compounds and surrogate recovery data from January 28, 2002.

NYC-WTC_000036712–000036728

Folder label: “GCMS X 12/7/01 A 1/2/02

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NYC 9/11 Public Portal Document

Quantitation Report (QT Reviewed)

Data File C:\HPCHEM\l\DATA\DEC2701\29563.D Vial: 36 . Acq On 28 Dec 2001 11:11 pm Operator: 209 GALOS Sample GC/MS SCAN 12/7 Inst : GC/MS 209 Mise Multiplr: 1.00 MS Integration Params: GOOFY.P Quant Time: Dec 29 0:00 2001 Quant Results File: GCMS1126.RES

Quant Method : C:\HPCHEM\1\METHODS\GCMS1126.M (RTE Integrator) Title : 209 625/TCLP calibration table Last Update : Fri Dec 28 15:11:00 2001 Response via : Initial Calibration DataAcq Meth : GCMS1126

Internal Standards R.T. Qlon Response Cone Units Dev(Min)

1) 1,4-Dichlorobenzene-d4 11.68 152 1359641 20.00 ug/1 -0.02 10) Naphthalene-d8 15.28 136 5190720 20.00 ug/1 -0.03 17) Acenaphthene-dlO 20.57- 164 2533069 20.00 ug/1 -0.01 29) Phenanthrene-diO 24.98 188 3810154 20.00 ug/1 -0.01 38) Chrysene-dl2 33.02 240 2314101 20.00 ug/1 -0.01 44) Perylene-dl2 37.12 264 1398621 20.00 ug/1 0.00

System Monitoring Compounds 37) 2,4-DDD 30.07 235 172793 4.13 ug/mL 0.00 Spiked Amount 5.000 Recovery = 82.60%

Target Compounds Qvalue 2) N-nitroso-dimethyl amine 5.30 74 510 N.D. 3) bis(2-Chloroethyl)ether 0.00 93 0 N.D. 4) 1,3-Dichlorobenzene 0.00 146 0 N.D. 5) 1,4-Dichlorobenzene 0.00 146 0 N.D. 6) 1,2-Dichlorobenzene 0.00 146 0 N.D. 7) 2,21 -oxybis(1-Chloropropan 0.00 45 0 . N.D. 8) N-Nitroso-di-n-propylamine 0.00 70 0 N.D. 9) Hexachloroethane 0.00 117 0 N.D. 11) Nitrobenzene 13.54 77 185 N.D. 12) Isophorone 13.86 82 188 N.D. 13) bis(2-Chloroethoxy)methane 14.94 93 108 N.D. 14) 1,2,4-Trichlorobenzene 0.00 180 0 N.D. 15) Naphthalene 15.34 128 2345 N.D. 16) Hexachlorobutadiene ' 0.00 225 0 N.D. 18) Hexachlorocyclopentadiene 0.00 237 0 N.D. 19) 2-Chloronaphthalene 0.00 162 0 N.D. 20) Dimethylphthalate 20.27 163 386 N.D. 21) 2,6-Dinitrotoluene 20.28 165 310 N.D. 22) Acenaphthylene 0.00 152 0 N.D. 23) Acenaphthene 0.00 153 0 N.D. 24) 2,4-Dinitrotoluene 21.37 165 172 N.D. 25) Diethylphthalate 22.11 149 2281 N.D. 26) 4-Chlorophenyl-phenylether 0.00 2 04 0 N.D. 27) Fluorene 0.00 166 0 N.D. 28) Azobenzen/ 1,2-Diphenylhyd 0.00 77 0 N.D.

(#) = qualifier out of range (m) = manual integration 29563.D GCMS1126.M Wed Jan 02 09:07:41 2002 Page 1

NYC-WTC_000036714

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NYC-WTC_000036714Source: NYC Law Department, mirrored locally

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Large multi-page laboratory data sheet containing sample analysis results and metadata for DEP GCMS records from January to February 2002.

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