GCMS analysis comments for sample AD29087, Dec 17 2001

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Data File : C:\HPCHEM\l\DATA\DEC1301\29087.D Vial: 15 Acq On : 13 Dec 2001 10:48 am Operator: 209 GALOS Sample : gems scan 11/30 Inst : GC/MS 209 Mise Multiplr: 1.00 MS Integration Params: LSCINT.P

Quant Method : C:\HPCHEM\1\METHODS\GCMS1126.M (RTE Integrator) Title : 209 625/TCLP calibration table Library : C:\DATABASE\NBS75K.L ********************************************************************* Peak Number 4 1,2-Benzenedicarboxylic acid, Concentration Rank 3

R.T. EstConc Area Relative to ISTD R.T.

32.76 0.60 ug/1 160486 Chrysene-dl2 33.01

Hit# Of 5 Tentative ID MW MolForm CAS# Qual 1 1,2-Benzenedicarboxylic acid, dipro 250 C14H18O4 000131-16-8 25 2 1-Propanone, 2,2-dichloro-3-hydroxy 218 C9H8C12O2 054824-08-7 17 3 Benzoic acid, phenyl ester 198 C13H10O2 000093-99-2 17 4 2-BromoisoPutyrophenone_____________ 226 ClOHllBrO 010409-54-8 16 Abundance Scan 3019 (32.762 min): 29087.D (-) m/z 104.9 100.00% 105 149

5000 77

51 32.40 32.60 32.80 33.00 42 J 67] , Gi 163 TTTTtm TITT TITUEumpponr TT)np"—208 96 122 u—nr m/z 149.00 86.18% m/z-> 20 30 40 50 60 70 80 90 100 110 120 130 140 150160 170 180 190 200 210 Abundance #33901:1,2-Benzenedicart>oxylicacicl, dipropyl ester 149

_ - 5000- 32.40 32.60 32.80 33.00 m/z 77.00 41.05% 31 43 56 65 76 93 104 121 Th n | i 11111 i'i 11111111111 p‘r r 111 l*n 11 n i T u i f T 167..... 1... —utCC Tm —uT 191—O... ’’ 209 miz-> 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210 Abundance #27040:1-Propanone, 2,2-dichloro-3-hydroxy-1-phenyl- 105 “MPoffr ok— 32.40 32.60 32.80 33.00 5000 m/z 51.00 9.87% 77

30 51 63 89 166 188 ———————— ■ • i1 ‘' • i125 '' ‘' I'"1T]1111 ITT TnUC—r m/z—> 20 30 40 50 60 70 80 90 100110 120 130 140 150 160 170 180 190 200 210 Abundance #22451: Benzoic acid, phenyl ester 105 IAAAWMAAWWw 32.40 32.60 32.80 33.00......... m/z 150.00 9.26% 5000

m/z—> 51 77

........... ........................................................................................................ 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210 .......... ‘ i ' 1 X -A 32.40 32.60 32.80 33.00

29087.D GCMS1126.M Thu Dec 13 14:45:17 2001 Page 4

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