GCMS calibration table for TCLP analysis, Nov 2001

NYC 9/11 Public Portal Document

Library Search Compound Report

Data File : C:\HPCHEM\1\DATA\JAN0802\28327.D Vial: 5 Acq On : 8 Jan 2002 4:16 pm Operator: 209 GALOS Sample : 508 Inst : GC/MS 209 Mise Multiplr: 1.00 MS Integration Params: LSCINT.P

Quant Method : C:\HPCHEM\1\METHODS\GCMS0103.M (RTE Integrator) Title : 209 625/TCLP calibration table Library : C:\DATABASE\NBS75K.L ********************************************************************* Peak Number 17 3-Isopropoxy-1,1,1,7,7,7-hexam Concentration Rank 15

R.T. EstConc Area Relative to ISTD R.T.

37.82 0.58 ug/1 137729 Perylene-dl2 36.91

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 3-Isopropoxy-/, 1,1,7,7,7-hexamethyl 576 C18H5207Si7 071579-69-6 23 2 Mercaptoacetic acid, bis (trimethyls 236 C8H20O2SSi2 006398-62-5 12 3 Silanamine/N- [2,6-dimethyl-4-[ (tri 281 C14H27NOS12 072088-09-6 11 4 Tris(trimgthylsilyl)borate 278 C9H27B03Si3 004325-85-3 10 Abundance Scan 3570 (37.821 min): 28327.D (-) m/z 73.00' 100.00% 73 147 i 5000 221 ___ / _ 281 355 T T T T TTT 1 327 L 40142 ..... 44 193 37.40 37.60 37.80 38.00 38.20 115 1 — 1 T* T.T.1 - , 253, '*1 1 14 11 m/z 147.00 65.32% miz-? 50 100 150 200 250 300 400 ' 450 350 500 ’ 550 ' Abundance #60503: 3-Isopropoxy-1,1,1,7,7,7-hexamethyl-3,5,5-tris(trim 73

5000 anap4-44** ,4-4 , , —pe 147 37.40 37.60 37.80 38.00 38.20 m/z 221.05 42.96% i l J... — b01 221 281 327 415 519 5. ......... ............ ' ■ i ' ■ m/Z—> 50 100 150 200 250 ' 300 350 400 450 500 550 ' Abundance 40049: Merpaptorcetic acid, bis(trimethyisilyt}- 73 147 37.40 37.60 37.80 38.00 38.20

I |

m/z-> Abundance 5000

45

73 104 193 TTTrreuurTuruuuuTuTT— TTTT TTTTT , । । , TT । । । । । । _50_ 100.__150 200 . 250 300 350 400 450 #39584: Silanamine, N-[2,6-dimethyl-4-[(trimethylsilyl)oxy]

209 221

281 500 550 .J m/z 281.00

T T T 24.54%

37.40 37.60 37.80 38.00 38.20 m/z 207.00 21.62% 5000 WWOw Vvw 45 251

120 147 179 ' ' i • ■ - I I T Inm i i ■ TTTTT.T T • ' i ' ' ■ ■ i ■ ■ m/z-> 50 100 150 200 250 300 350 400 450 500 550 37.40 37.60 37.80 38.00 38.20

28327.D GCMS1126.M Wed Jan 09 09:15:59 2002 Page 17

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