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GCMS analysis results for sample AD26681, Dec 10 2001

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Laboratory report documenting GCMS analysis of sample AD26681 identifying unknown compounds on December 10, 2001.

NYC-WTC_000032079–000032092

Folder label: “GCMS X 11/7/01 A 12/6/01

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NYC 9/11 Public Portal Document

Library Search Compound Report

Data File C:\HPCHEM\l\DATA\DEC0401\26681.D Vial: 2 Acq On 4 Dec 2001 11:44 am Operator: GALOS Sample gc/ms unknown Inst : GC/MS Ins Mise Multiplr: 1.00 MS Integration Params: LSCINT.P

Quant Method : C:\HPCHEM\1\METHODS\NP112701.M (RTE Integrator) Title : 208 625/TCLP calibration table Library : C:\DATABASE\NBS75K.L ********************************************************************* Peak Number 2 1-Butanol Concentration Rank 7

R.T. EstConc Area Relative to ISTD R.T.

5.06 0.61 ng/uL 256098 1,4-Dichlorobenzene-d4 11.87

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 1-Butanol / 74 C4H10O 000071-36-3 32 2 Aziridine, 1-methyl- 57 C3H7N 001072-44-2 9 3 Ethane/diazo- 56 C2H4N2 001117-96-0 9 4 1-Butanol, 2-methyl - , (S) -______ 88 C5H120 _______ 001565-80-6 9 Abundance Scan 24 (5.065 min): 26681.D (-) m/z 41.05 100.00% 41 56 59

5000 - 71 45 4.90 5.00 5.10 5.20 5.30 5.40 5.50 38, I . . . . I . . . ' I ' • 1 . I 1 ' 1 ' I 1 ' . 1 I 1 1 I 1 I ' 1 I 1 I 1 — '50H 53 — | I. .... T-T-p-m-T m/ z 56.10 84.48% m/z-> 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 Abundance 1 #62584: 1-Butanol 41 56

............. T’TETC’EEIIUEIITETETT’TTT 5000 T’T 4.90 5.00 5.10 5.20 5.30 5.40 5.50 m/z 59.10 79.96% 35 | 1553l N.. _ l» ‘ 1 l • • • « TTT I I I • I I I I I «< I I I I « I I > til I I । ।11'11' ■ ■' ।'' ■ ■ ।' ■' ■ । m/z—> 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 Abundance #86: Aziridine, 1 -methyl- 42

4.90 5.00 5.10 5.20 5.30 5.40 5.50 5000 57 m/z 4 . 05 69.54%

NN 15 27 30 1 54 I'11TTT ।।।।।।।1।1।. TT‘t"‘IttttTttrrI‘"11i m/z-> 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 Abundance #71: Ethane, diazo- I ' ' ' ' I 11 11 1 I TTTTr 27 4.90 5.00 5.10 5.20 5.30 5.40 5.50

56 m/ 43.00 57.30% 5000

14 ■ ■ i ■ ....... ill............ 50 53 , ■ ■ i1 ■ ' ■ i' ■ ■ ' i ■' 1 111 1 ' ■ I' ' 1 ■ I • I ' 1 1 ’ I 1 ' 1 1 1 1 1 ’ ' 1 1 1 1 1 I 7.. ... m/z-> 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 4.90 5.00 5.10 5.20 5.30 5.40 5.50

26681.D NP112701.M Fri Dec 07 13:12:23 2001 Page 2

NYC-WTC_000032085

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